7058-55-1Relevant articles and documents
Zinc(II) and cadmium(II) complexes with o-hydroxybenzoic acid or o-aminobenzoic acid and 2-methylimidazole: IIIR spectra, X-ray diffraction studies and thermal analysis
Olczak-Kobza, Maria,Mrozek, Agnieszka
, p. 553 - 560 (2009/08/15)
Mixed complexes of the type: Zn(Hsal)2(2-MeHim)2, Zn(Han)2(2-MeHim)2, Cd(Hsal)2(2-MeHim) 2, Cd(Han)2(2-MeHim)2, where Hsal=OHC 6H4COO-, Han=NH2C6H 4COO-, 2-MeHim=2-methylimidazol) have been synthesized and characterized by IR spectroscopic and X-ray diffraction studies. Single-crystal X-ray structure of Cd(Hsal)2(2-MeHim)2 has been obtained. Thermal behaviour of the compounds was investigated by thermal analysis (TG, DTG, DTA). A coupled TG-MS system was used to analyse the principal volatile products of complexes. Thermal decomposition pathways have been postulated.