70625-09-1

Basic information

• Product Name: Thiazolium, 4-methyl-3-(phenylmethyl)-2-(phenylthio)-, tetrafluoroborate(1-)
• Synonyms: Thiazolium, 4-methyl-3-(phenylmethyl)-2-(phenylthio)-, tetrafluoroborate(1-)
• CAS NO: 70625-09-1
• Molecular Formula: BF₄*C₁₇H₁₆NS₂
• Molecular Weight: 0
• Mol File: 70625-09-1.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Thiazolium, 4-methyl-3-(phenylmethyl)-2-(phenylthio)-, tetrafluoroborate(1-)(CAS DataBase Reference)
• NIST Chemistry Reference: Thiazolium, 4-methyl-3-(phenylmethyl)-2-(phenylthio)-, tetrafluoroborate(1-)(70625-09-1)
• EPA Substance Registry System: Thiazolium, 4-methyl-3-(phenylmethyl)-2-(phenylthio)-, tetrafluoroborate(1-)(70625-09-1)

Safety Data

• Hazardous Substances Data: 70625-09-1(Hazardous Substances Data)

Upstream product

• 14204-27-4 N-phenylthiophthalimide 
• 76756-47-3 3-benzyl-4-methylthiazolium tetrafluoroborate 
• 4356-66-5 3-Benzyl-4-methylthiazolium bromide 

Relevant articles and documents

α-Keto Acid Dehydrogenases: A Chemical Model

A model system for the involvement of lipoic acid in α-keto acid dehydrogenase systems is described. 2-(α-Hydroxyethyl)-3-benzyl-4-methylthiazolium tetrafluoroborate (6) serves as precursor for an analogue of the thiamine-bound active aldehyde 1 in the natural system.The model active aldehyde 7 reacts with linear disulfides, yielding thiols and thioesters.The 1,2-dithiolane, methyl lipoate (14), is unreactive under model reaction conditions.The tetrahedral intermediate which would be formed from methyl lipoate (14) plus an active aldehyde analogue 19 has been generated in a nonbiomimetic fashion.The synthetic tetrahedral intermediate 17 undergoes the reverse of the biological, disulfide reductive cleavage reaction.