707-34-6Relevant articles and documents
Hollow sphere formation from a three-dimensional structure composed of an adamantane-based cage
Tominaga, Masahide,Ohara, Kazuaki,Yamaguchi, Kentaro,Azumaya, Isao
, p. 6738 - 6742 (2014)
An adamantane-based cage with a three-dimensional (3D) framework was synthesized by the copper-mediated acetylene coupling reaction, in which two 1,3,5-triethynyladamantane units were linked by phenyldiacetylenic bridges possessing ester groups. X-ray cry
A process for the preparation of adamantane triols
-
Paragraph 0069-0075, (2017/04/14)
The invention provides a preparation method for adamantanetriol. The method is characterized by consisting of two phases: phase one, reacting adamantane with bromine to generate 1, 3, 5-tribromoadamantane; phage 2, under the action of silver sulfate and concentrated sulfuric acid, letting 1, 3, 5-tribromoadamantane generate adamantanetriol. According to the synthesis method provided by the invention, by selecting the reaction conditions of each step, like reaction temperature, reaction ratio, reaction time, reaction feedstock and the like, the problems of difficult purification, low reaction yield, low product purity, inapplicability to large-scale industrial production and the like in existing technical disclosures can be overcome.
Synthesis of Well-Defined Tower-Shaped 1,3,5-Trisubstituted Adamantanes Incorporating a Macrocyclic Trilactam Ring System
Li, Quan,Jin, Changshu,Petukhov, Pavel A.,Rukavishnikov, Aleksey V.,Zaikova, Tatiana O.,Phadke, Avinash,LaMunyon, Donald H.,Lee, Melissa D.,Keana, John F. W.
, p. 1010 - 1019 (2007/10/03)
We describe the synthesis of two novel well-defined tower-shaped 1,3,5-trisubstituted adamantanes 30 and 33 that incorporate a macrocyclic trilactam ring system. Each nanoscale molecule has a broad tripodal base consisting of three identical sulfur-contai