70734-74-6Relevant articles and documents
Polyphenylene oligomers and polymers
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Example 1A(d), (2008/06/13)
The present invention refers to aromatic monomers containing at least one cyclopentadienone moiety and at least one acetylene moiety and oligomers, uncured polymers and cured polymers comprising the reaction product thereof.
Chemoselective oxidation of carbon-carbon double or triple bonds to 1,2-diketones with DMSO-based reagents
Yusubov,Filimonov,Vasilyeva,Chi
, p. 1234 - 1236 (2007/10/02)
HBr/DMSO selectively oxidizes the double bond in (E)-1-(2-phenylethenyl)-4-(phenylethynyl)benzene (1) to 1,2-diketone 2. However, 12/DMSO and PdCl2/DMSO oxidize only the triple bond in 1 to 1,2-diketone 3. A similar trend of chemoselectivity is shown for the oxidation of (E)-1,4-diphenyl-1-buten-3-yne (6) with the DMSO-based reagents.