7077-62-5

Basic information

• Product Name: trimethyl-N-phenyl-phosphorimidate
• Synonyms: trimethyl-N-phenyl-phosphorimidate
• CAS NO: 7077-62-5
• Molecular Weight: 215.189
• Mol File: 7077-62-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: trimethyl-N-phenyl-phosphorimidate(CAS DataBase Reference)
• NIST Chemistry Reference: trimethyl-N-phenyl-phosphorimidate(7077-62-5)
• EPA Substance Registry System: trimethyl-N-phenyl-phosphorimidate(7077-62-5)

Safety Data

• Hazardous Substances Data: 7077-62-5(Hazardous Substances Data)

Upstream product

• 622-37-7 Phenyl azide 
• 121-45-9 phosphorous acid trimethyl ester 

Downstream Products

• 7006-95-3 O,O-dimethyl-N-methyl-N-phenyl-phosphoramidate 
• 102969-22-2 2,2,4-Trimethoxy-1-phenyl-1,4-dihydro-2λ⁵-[1,2]azaphosphinine-3,4,5,6-tetracarboxylic acid tetramethyl ester 
• 102969-21-1 2,2,2-Trimethoxy-1-phenyl-1,2-dihydro-2λ⁵-[1,2]azaphosphinine-3,4,5,6-tetracarboxylic acid tetramethyl ester 
• 102969-04-0 C₁₅H₂₀NO₇P 
• 133827-76-6 O,O-dimethyl N,N-deuteromethyl phenylamidophosphate 
• 133827-75-5 O,O-dideuteromethyl N,N-methylphenylamidophosphate 
• 133827-74-4 C₉H₅⁽²⁾H₉NO₃P 
• 58046-12-1 dimethyl N-phenyl-phosphoramidate 

Relevant articles and documents

Reactions de tris(alcoxy)iminophosphanes avec l'acetylene dicarboxylate de methyle: ylure, phosphonate et phosphorane

The tris(alkoxy) N-phenyl iminophosphanes react under mild conditions with acetylenic carboxylates to give phosphorus ylides with a β carbonyl group.These compounds, well characterized in the reaction mixture, have not been isolated.They are highly reactive and depending on the nature of substituents on phosphorus atom; give phosphonates, phosphoranes and cyclic ylides.

INDUCTIVE AND STERIC EFFECTS IN THE STAUDINGER REACTION

The sterically unhindered mode of the electrophilic addition of phenyl azide to trivalent phosphorus compounds and the inductive control in this initial step of the Staudinger reaction have been observed and discussed.