70774-46-8Relevant articles and documents
A versatile synthetic platform based on strained propargyl amines
He, Zhi,Yudin, Andrei K.
supporting information; experimental part, p. 1607 - 1610 (2010/06/16)
"Chemical Equation Presented" Divergent reactivity: Various ethynylaziridines behave as strained propargyl amines and can be directly converted into unprotected α-amino allenes by a highly diastereoselective SN2′ hydride delivery (see scheme). Additional reaction routes involve chemo- and regioselective transformation into either bicyclic aziridine/ enol ethers or highly strained azirine alkynes.
MASS SPECTROMETRIC DECOMPOSITION OF β-PHENYLOXIRANECARBOXYLIC ESTERS
Anisimova, O. S.,Chistyakov, V. V.,Bokanov, A. I.,Shvedov, V. I.,Sheinker, Yu. N.
, p. 1058 - 1063 (2007/10/02)
The electron-impact mass spectra of the E- and Z-isomers of the α,β-methyl substituted esters of β-phenyloxiranecarboxylic acids have been studied.
Chromatographic Resolution of Enantiomers with Natural Polymers
Konrad, Gerd,Musso, Hans
, p. 1956 - 1967 (2007/10/02)
Cheap, chiral, natural polymers have been tested as stationary phases for the chromatographic resolution of the enantiomers of several very different racemates.Silk, wool, and cellulose are not suitable.Potato starch can be used well in special cases.Hesse's and Hagel's cellulose triacetate finds widest application, as shown by several new examples.This property results from a genuine chiral tertiary structure not to be destroyed during preparation.
