70848-22-5Relevant articles and documents
Synthesis of mono-, di-, and triaminobismuthanes and observation of C-C coupling of aromatic systems with bismuth(iii) chloride
Hering-Junghans, Christian,Schulz, Axel,Thomas, Max,Villinger, Alexander
, p. 6053 - 6059 (2016)
The reaction of lithium N-trimethylsilyl-amides of the type RN(SiMe3)Li with bismuth(iii) chloride yielded mono-, di- or triaminobismuthanes depending on the sterical demand of the anilide ligand R and the used stoichiometry. For the bulky Mes? substituent the reaction with BiCl3 resulted in the formation of a C-C coupling product as the main product besides a small amount of the expected Mes?N(SiMe3)BiCl2.