7086-13-7

Basic information

• Product Name: 2,4,6-triphenyl-1,4-dihydro-1,3,5-triazine
• Synonyms: 1,3,5-triazine, 1,2-dihydro-2,4,6-triphenyl-; 2,4,6-Triphenyl-1,2-dihydro-1,3,5-triazine
• CAS NO: 7086-13-7
• Molecular Formula: C₂₁H₁₇N₃
• Molecular Weight: 311.3798
• Mol File: 7086-13-7.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 473.2°C at 760 mmHg
• Flash Point: 240°C
• Density: 1.15g/cm³
• Vapor Pressure: 4E-09mmHg at 25°C
• Refractive Index: 1.646
• CAS DataBase Reference: 2,4,6-triphenyl-1,4-dihydro-1,3,5-triazine(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4,6-triphenyl-1,4-dihydro-1,3,5-triazine(7086-13-7)
• EPA Substance Registry System: 2,4,6-triphenyl-1,4-dihydro-1,3,5-triazine(7086-13-7)

Safety Data

• Hazardous Substances Data: 7086-13-7(Hazardous Substances Data)

Usage

Triazine derivative

A chemical compound derived from the base structure of a triazine, which is a six-membered heterocyclic ring system consisting of 3 carbon atoms and 3 nitrogen atoms.

Three phenyl groups

The presence of 3 phenyl groups (a benzene ring with a hydrogen atom replaced by a side chain) attached to the triazine ring, which contributes to the compound's structure and reactivity.

Building block for organic synthesis

2,4,6-triphenyl-1,4-dihydro-1,3,5-triazine is commonly used as a starting material for the synthesis of various organic molecules, particularly in medicinal chemistry and material science.

Unique structure and reactivity

The compound's specific arrangement of atoms and functional groups give it special properties, making it a valuable intermediate for the preparation of pharmaceuticals, agrochemicals, and advanced materials.

Electron-transporting properties

2,4,6-triphenyl-1,4-dihydro-1,3,5-triazine has the ability to move electrons through its structure, which is an important property for use in electronic devices.

Potential applications in OLEDs

Due to its electron-transporting properties, the compound has potential applications in the development of organic light-emitting diodes (OLEDs), which are used in various display technologies and lighting applications.

Upstream product

• 100-47-0 benzonitrile 
• 71-43-2 benzene 
• 493-77-6 2,4,6-triphenyl-1,3,5-triazine 
• 1670-14-0 benzamidine monohydrochloride 
• 100-52-7 benzaldehyde 
• 618-39-3 benzamidin 

Downstream Products

• 1345690-20-1 2,4,6-triphenyl-1,3,5-triazine-1-oxide 
• 493-77-6 2,4,6-triphenyl-1,3,5-triazine 
• 1345690-21-2 2-methyl-2,4,6-triphenyl-1,2-dihydro-1,3,5-triazine-1-oxide 
• 1345690-22-3 2,2,4,6-tetraphenyl-1,2-dihydro-1,3,5-triazine-1-oxide 
• 1345690-28-9 2-methyl-2,4,6-triphenyl-1,2-dihydro-1,3,5-triazinyl-1-oxy 
• 1345690-29-0 2,2,4,6-tetraphenyl-1,2-dihydro-1,3,5-triazinyl-1-oxy 

Relevant articles and documents

MCRs reshaped into a switchable microwave-assisted protocol toward 5-aminoimidazoles and dihydrotriazines

A tunable microwave-assisted protocol for the synthesis of two biologically relevant families of heterocycles has been designed. Via a simple switch of reaction conditions, the same starting materials can be engaged in either an improved synthesis of the dihydrotriazine scaffold or a novel, first-in-class MCR to render the challenging 5-aminoimidazole nucleus in a single step. An additional first-in-class MCR is also reported utilizing guanidines to afford 2,5-aminoimidazoles.

1,2-Dihydrotriazinyl-N-oxy free radicals

Triazinyl-N-oxy free radicals, 2-methyl-2,4,6-triphenyl-1,2-dihydro-1,3,5- triazinyl-1-oxy (6 a), 2,2,4,6-tetraphenyl-1,2-dihydro-1,3,5-triazinyl-1-oxy (6 b), 2,2-dimethyl-4,6-diphenyl-1,2-dihydro-1,3,5-triazinyl-1-oxy (13), and 2,6-dimethyl-2,4-diphenyl-1,2-dihydro-1,3,5-triazinyl-1-oxy (14), in which the unpaired electron is delocalized over three nitrogen atoms, have been prepared and characterized. A method has been devised for introducing an N-oxide function into the triazinyl core. Then, by using a Grignard reagent, substitution α to the N-oxide group was achieved and the resulting 1,2-dihydrotriazine- N-oxide oxidized into the corresponding nitroxide. Solution EPR spectra exhibit hyperfine splitting that confirms spin delocalization over the three nitrogen atoms of the triazinyl ring. They also show that spin delocalization diminishes with increasing distance for the coupling and is largest for nitrogen N1 and weakest for N5. Free radicals 6 a and 13 are stable in the solid state and have been characterized by X-ray diffraction, but they tend to gradually degrade in solution. In the solid state, these two free radicals are arranged into antiferromagnetically exchange-coupled pairs, J=-5.2(6) for 6 a and -3.7(4) cm-1 for 13 (H=-2 JS1S2). Copyright