70975-34-7

Basic information

• Product Name: N-bromo-S,S-diphenyl sulfoximine
• Synonyms: N-bromo-S,S-diphenyl sulfoximine
• CAS NO: 70975-34-7
• Molecular Weight: 296.188
• Mol File: 70975-34-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N-bromo-S,S-diphenyl sulfoximine(CAS DataBase Reference)
• NIST Chemistry Reference: N-bromo-S,S-diphenyl sulfoximine(70975-34-7)
• EPA Substance Registry System: N-bromo-S,S-diphenyl sulfoximine(70975-34-7)

Safety Data

• Hazardous Substances Data: 70975-34-7(Hazardous Substances Data)

Upstream product

• 945-51-7 1,1'-sulfinylbisbenzene 
• 72277-48-6 diphenyl-N-<(2-chloro-3,3-dimethyl)butyl>sulphoximide 
• 70975-35-8 S,S-diphenyl-N-chlorosulfoximine 
• 22731-83-5 S,S-diphenylsulphoximine 

Downstream Products

• 5401-62-7 1,2-dibromocyclohexane 
• 22731-83-5 S,S-diphenylsulphoximine 
• 72277-52-2 diphenyl-N-(2-bromocyclohexyl)sulphoximide 
• 1521-51-3 rac-3-bromocyclohexene 
• 70975-35-8 S,S-diphenyl-N-chlorosulfoximine 
• 72277-53-3 C₁₇H₂₀ClNOS 
• 72277-54-4 C₂₀H₂₆ClNOS 
• 72277-51-1 diphenyl-N-(2-chlorocyclohexyl)sulphoximide 
• 97383-39-6 S,S-diphenyl-N-(α-toluenesulfenyl)sulfoximine 
• 72277-49-7 diphenyl-N-<(2-bromo-3,3-dimethyl)butyl>sulphoximide 

Relevant articles and documents

N -Trifluoromethylthiolated Sulfoximines

Air- and moisture-stable N-trifluoromethylthio sulfoximines have been prepared from N-H-sulfoximines via the corresponding N-Br derivatives in excellent yields. The two-step process starts with an easy-to-perform bromination at the sulfoximine nitrogen, followed by a reaction with silver trifluoromethanethiolate. A one-pot reaction sequence allows difficult to prepare products to be obtained.

Homolytic Reaction of N-Halogenosulphoximides with Olefins and Toluene

Homolytic addition reaction of N-halogenosulphoximides, i.e. diphenyl-N-chlorosulphoximide (1), diphenyl-N-bromosulphoximide (2), and methylphenyl-N-chlorosulphoximide (3), to olefins such as t-butylethylene and cyclohexene under both u.v. irradiation and thermolysis in the presence of a radical initiator was found to afford the corresponding N-alkylated sulphoximides, which are presumed to be formed via the initial addition of the sulphoximidoyl radical.Meanwhile, homolytic bromination of toluene with N-bromosulphoximide (2) proceeded readily by u.v. irradiation, or by thermal reaction in the presence of a radical initiator, to afford benzyl bromide.However, chlorination of toluene was sluggish with N-chlorosulphoximides (1) and (3). α-Bromination was interpreted in terms of a chain process involving bromine molecules like the 'Goldfinger mechanism', but not via that involving the sulphoximidoyl radical.