711014-90-3

Basic information

• Product Name: N-(4-chlorophenyl)methyl-N-(4-chlorophenyl)methyleneamine N-oxide
• CAS NO: 711014-90-3
• Molecular Weight: 280.153
• Mol File: 711014-90-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: N-(4-chlorophenyl)methyl-N-(4-chlorophenyl)methyleneamine N-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-chlorophenyl)methyl-N-(4-chlorophenyl)methyleneamine N-oxide(711014-90-3)
• EPA Substance Registry System: N-(4-chlorophenyl)methyl-N-(4-chlorophenyl)methyleneamine N-oxide(711014-90-3)

Safety Data

• Hazardous Substances Data: 711014-90-3(Hazardous Substances Data)

Upstream product

• 622-95-7 4-chlorobenzyl bromide 
• 40861-08-3 N,N-bis(p-chlorobenzyl)hydroxylamine 

Downstream Products

• 51307-68-7 N-4-chlorobenzylhydroxylamine 
• 104-88-1 4-chlorobenzaldehyde 

Relevant articles and documents

S -Tetrazine: Robust and Green Photoorganocatalyst for Aerobic Oxidation of N,N-Disubstituted Hydroxylamines to Nitrones

Efficient photocatalytic aerobic oxidative dehydrogenation reactions of N,N-disubstituted hydroxylamines to nitrones were developed with an in situ generated photocatalyst based on commercially available 3,6-dichlorotetrazine. This process affords a wide range of nitrones in high yields under mild conditions. In addition, an oxidative (3+3) cycloaddition between an oxyallyl cation precursor and a hydroxylamine was also developed.

Mechanism of the 10-methylacridinium ion-sensitized photooxidation of N,N-dibenzylhydroxylamine and its derivatives in acetonitrile

The 10-methylacridinium ion (MA+)-sensitized photooxidation of substituted N,N-dibenzylhydroxylamines (1) in acetonitrile occurred mainly by a superoxide ion mechanism to give N-benzylidenebenzylamine N-oxides (2) and hydrogen peroxide quantitatively. Analysis of substituent effects on the limiting quantum yield for formation of 2 showed that back electron transfer (ET) from the 10-methylacridinyl radical (MA.) to the radical cation 1+. proceeds in the Marcus 'normal region'. In addition, this back ET was found to take place in preference to one-electron reduction of O2 by MA..

Cyanoanthracene-sensitized Photooxidations of N,N-Dibenzylhydroxylamine and its Derivatives; Observation of the Marcus 'Inverted Region' in Back Electron Transfer within Geminate Radical Ion Pairs

Back electron transfer within geminate radical ion pairs formed by electron transfer from the title hydroxylamines to singlet 9-cyano- and 9,10-dicyano-anthracenes in acetonitrile is shown to occur in the Marcus 'inverted region' and 'normal region', resp