7111-66-2Relevant articles and documents
Dialkyl Ether Formation by Nickel-Catalyzed Cross-Coupling of Acetals and Aryl Iodides
Arendt, Kevin M.,Doyle, Abigail G.
, p. 9876 - 9880 (2015/08/19)
A new substrate class for nickel-catalyzed C(sp3) cross-coupling reactions is reported. α-Oxy radicals generated from benzylic acetals, TMSCl, and a mild reductant can participate in chemoselective cross-coupling with aryl iodides using a 2,6-bis(N-pyrazolyl)pyridine (bpp)/Ni catalyst. The mild, base-free conditions are tolerant of a variety of functional groups on both partners, thus representing an attractive C-C bond-forming approach to dialkyl ether synthesis. Characterization of a [(bpp)NiCl] complex relevant to the proposed catalytic cycle is also described.
C-F bond cleavage by intramolecular SN2 reaction of alkyl fluorides with O- and N-nucleophiles
Zhang, Laijun,Zhang, Wei,Liu, Jun,Hu, Jinbo
supporting information; experimental part, p. 2850 - 2853 (2009/08/08)
The nueleophilic substitution of alkyl fluorides was achieved in the intramolecular reactions with O- and N-nucleophiles. The intramolecular defluorinative cyclization reaction was influenced by the nature of nucleophiles, the size of the ring to be forme
Preparation of functionalized arylmagnesium reagents bearing an o-chloromethyl group
Delacroix,Berillon,Cahiez,Knochel
, p. 8108 - 8110 (2007/10/03)
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