71183-35-2Relevant articles and documents
Influence of the steric hindrance of the aryl group of pentavalent triarylbismuth derivatives in ligand coupling reactions
Fedorov, Alexey,Combes, Sebastien,Finet, Jean-Pierre
, p. 1341 - 1352 (1999)
Tris(ortho-tolyl)bismuth dichloride derivatives react with nucleophiles under basic conditions to give good to high yields of the C-arylated substrates. Under the same conditions, trimesitylbismuth dichloride affords only poor yields of the C-mesitylated substrates. Similar influence of the substitution pattern of tris(ortho-tolyl)bismuth diacetate derivatives was observed in the copper-catalysed arylation of hydroxyl or amino groups.