71190-35-7Relevant articles and documents
Synthesis and characterization of new azobenzene-containing bis pentacyanoferrate(II) stoppered push-pull [2]rotaxanes, with α- And β-cyclodextrin. Towards highly medium responsive dyes
Deligkiozi, Ioanna,Voyiatzis, Evangelos,Tsolomitis, Athanase,Papadakis, Raffaello
, p. 709 - 712 (2015)
The solvatochromic behavior of novel synthesized azo-containing viologen-based rotaxanes, combining push-pull linear and α or β-cyclodextrin macrocyclic components is examined. These rotaxanes are stoppered by pentacyanoferrate(II) units. The latter stabi
Synthese von 6,6'-Biazulenyl
Hanke, Manfred,Jutz, Christian
, p. 31 - 32 (1980)
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Face selectivity of inclusion complexation of viologens with ?2-cyclodextrin and 6-O-(2-sulfonato-6-naphthyl)-?2-cyclodextrin
Park, Joon Woo,Song, Hee Eun,Lee, Soo Yeon
, p. 7186 - 7192 (2002)
Face selectivity in binding of methyloctyl viologen (C1C8V2+: 1) and adamantylmethyl viologen (AdaC1V2+: 2) with ?2-CD and 6-O-(2-sulfonato-6-naphthyl)-?2-CD (?2-CD-NS: 4) has been investigated. Circu
Formation of ring-in-ring complexes between crown ethers and rigid TVBox8+
Sun, Junling,Frasconi, Marco,Liu, Zhichang,Barnes, Jonathan C.,Wang, Yuping,Chen, Dongyang,Stern, Charlotte L.,Fraser Stoddart
, p. 1432 - 1435 (2015)
A rigid octacationic tetraviologen-based cyclophane, TVBox8+, is reported. It possesses a highly electron-deficient rectangular cavity with a length of 23 ? and width of 6.1 ? and is capable of encapsulating either two small π-aromatic guest mo
Pentacyanoiron(II) as an electron donor group for nonlinear optics: Medium-responsive properties and comparisons with related pentaammineruthenium(II) complexes
Coe, Benjamin J.,Harries, Josephine L.,Helliwell, Madeleine,Jones, Lathe A.,Asselberghs, Inge,Clays, Koen,Brunschwig, Bruce S.,Harris, James A.,Garin, Javier,Orduna, Jesus
, p. 12192 - 12204 (2006)
In this article, we describe a series of complex salts in which electron-rich {FeII(CN)5}3- centers are coordinated to pyridyl ligands with electron-accepting N-methyl/aryl-pyridinium substituents. These compounds have bee
Self-assembly of cucurbit[7]uril based triangular [4]molecular necklaces and their fluorescence properties
Samanta, Soumen K.,Brady, Kimberly G.,Isaacs, Lyle
, p. 2756 - 2759 (2017)
Self-assembly of rigid-rod dipyridine ligand 1 with M(en)(NO3)2 (M = Pd, Pt) affords triangular (3, 5) and square (4, 6) supramolecular coordination complexes (SCCs). The binding affinity of 1 toward CB[n]-type containers results in the formation of triangular [4]molecular necklaces ([4]MNs, 7-10) by either one-pot or post complexation approaches as evidenced by 1H NMR, diffusion ordered spectroscopy, and ESI-MS.
Rational Design of Pore Size and Functionality in a Series of Isoreticular Zwitterionic Metal-Organic Frameworks
Aulakh, Darpandeep,Islamoglu, Timur,Bagundes, Veronica F.,Varghese, Juby R.,Duell, Kyle,Joy, Monu,Teat, Simon J.,Farha, Omar K.,Wriedt, Mario
, p. 8332 - 8342 (2018)
The isoreticular expansion and functionalization of charged-polarized porosity has been systematically explored by the rational design of 11 isostructural zwitterionic metal-organic frameworks (ZW-MOFs). This extended series of general structural composition {[M3F(L1)3(L2)1.5]·guests}n was prepared by employing the solvothermal reaction of Co and Ni tetrafluoroborates with a binary ligand system composed of zwitterionic pyridinium derivatives and traditional functionalized ditopic carboxylate auxiliary ligands (HL1·Cl = 1-(4-carboxyphenyl)-4,4′-bipyridinium chloride, Hcpb·Cl; or 1-(4-carboxyphenyl-3-hydroxyphenyl)-4,4′-bipyridinium chloride, Hchpb·Cl; and H2L2 = benzene-1,4-dicarboxylic acid, H2bdc; 2-aminobenzene-1,4-dicarboxylic acid, H2abdc; 2,5-dihydroxy-1,4-benzenedicarboxylic acid, H2dhbdc; biphenyl-4,4′-dicarboxylic acid, H2bpdc; or stilbene-4,4′-dicarboxylic acid, H2sdc). Single-crystal structure analyses revealed cubic crystal symmetry (I-43m, a = 31-36 ?) with a 3D pore system of significant void space (73-81%). The pore system features three types of pores being systematically tunable in size ranging from 17.4 to 18.8 ? (pore I), 8.2 to 12.8 ? (pore II), and 4.8 to 10.4 ? (pore III) by the choice of auxiliary ligands. All members of this series have noninterpenetrating structures and exhibit robust architectures, as evidenced by their permanent porosity and high thermal stability (up to 300 °C). The structural integrity and specific surface areas could be systematically optimized using supercritical CO2 exchange methods for framework activation resulting in BET surface areas ranging from 1250 to 2250 m2/g. Most interestingly, as a structural landmark, we found the pore surfaces lined with charge gradients employed by the pyridinium ligands. This key feature results in significant adsorption of carbon dioxide and methane which is attributed to polarization effects. With this contribution we pioneer the reticulation of pyridinium building blocks into extended zwitterionic networks in which specific properties can be targeted.
Novel viologen compound and preparation thereof
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, (2020/07/23)
The invention relates to novel viologen compounds and a preparation method thereof. Specifically, the invention provides a type of compounds with a structure shown by a formula I. The definitions of the groups are as in the specifications. The compounds of the formula I provided by the invention can be widely applied in the aspects of soft matter material construction, photoelectric materials, and solar cells.