71201-23-5

Basic information

• Product Name: 10,12-Octadecadienoic acid, 9-oxo-, methyl ester, (E,E)-
• CAS NO: 71201-23-5
• Molecular Formula: C19H32O3
• Molecular Weight: 308.461
• Mol File: 71201-23-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 10,12-Octadecadienoic acid, 9-oxo-, methyl ester, (E,E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 10,12-Octadecadienoic acid, 9-oxo-, methyl ester, (E,E)-(71201-23-5)
• EPA Substance Registry System: 10,12-Octadecadienoic acid, 9-oxo-, methyl ester, (E,E)-(71201-23-5)

Safety Data

• Hazardous Substances Data: 71201-23-5(Hazardous Substances Data)

Upstream product

• 112-63-0 Methyl linoleate 
• 157085-57-9 (10E,12E,9S)-Methyl 9-hydroxyoctadeca-10,12-dienoate 
• 108-94-1 cyclohexanone 

Downstream Products

• 1842-70-2 methyl 9-oxooctadecanoate 

Relevant articles and documents

Synthesis of the 9-oxo-diene derivative of methyl dimorphecolate by an efficient Oppenauer oxidation procedure

Oxidation of methyl dimorphecolate (1) to methyl 9-oxo-10,12-E,E-octadecadienoate (2) has been studied, using Oppenauer conditions. Acetone and cyclohexanone have been used as oxidizing ketones. Combination of cyclohexanone with inert solvents has been pe

New geometric isomers of oxooctadecadienoate in copper-catalyzed decomposition products of linoleate hydroperoxide

Methyl linoleate hydroperoxide produced by autoxidation was refluxed with 10-4 M Cu-naphthenate in benzene. Two new geometrical isomers of oxooctadecadienoate (compounds I and II) were found in addition to the four known isomers. They were isolated by a Sephadex LH-20 column chromatography with chloroform-hexane (2:1) and purified by HPLC on Nucleosil 100-5 and Zorbax ODS columns. UV, IR, MS, and 1H-NMR spectra were measured. The geometry of conjugated dienes were assigned from the coupling constants of the olefinic protons. Compounds I and II were identified as 13-oxo-trans-9, cis-11- and 9-oxo-cis-10, trans-12-octadecadienoate, respectively. Each of them had a cis double bond adjacent to the oxo group. The hydroperoxides of the same geometry as compounds I and II were also detected in autoxidation products.