713147-59-2Relevant articles and documents
Practical synthesis of chlorosilyl-functionalized triphenylphosphanes
Quintard, Delphine,Keller, Manfred,Breit, Bernhard
, p. 905 - 908 (2004)
A practical synthesis of ortho-dialkylchlorosilyl-functionalized triarylphosphanes has been developed. An X-ray crystal structure analysis of phosphane 3 unambiguously confirmed the constitution of the new phosphane functionalized chlorosilanes. It also showed an interesting P/Si interaction, which may render this compound a model for the early stages of the mechanism of SN2 nucleophilic displacement at silicon.
A composite material containing organic and inorganic organophosphine organophosphine compd. and use thereof
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, (2017/02/02)
PROBLEM TO BE SOLVED: To provide a phosphine compound utilizable as a silane coupling agent usable as a precursor for forming a covalent bond with an inorganic oxide by introducing a silyl group having a leaving substituent to the phosphine compound.SOLUTION: The phosphine compound is represented by formula (1), wherein Rand Rare each independently an aryl group or an alkyl group; Y is an aryl group or an alkyl group; X, when Y is an aryl group, is one group selected from the group consisting of a halogen atom, an alkoxy group, a hydroxy group and an amino group, and when Y is an alkyl group, is one group selected from the group consisting of an alkoxy group, a hydroxy group and an amino group; and n is an integer of 1 to 3.