71482-65-0

Basic information

• Product Name: 2-Propanone, 1-chloro-3-(trimethylsilyl)-
• Synonyms: 2-Propanone, 1-chloro-3-(trimethylsilyl)-
• CAS NO: 71482-65-0
• Molecular Formula: C₆H₁₃ClOSi
• Molecular Weight: 164.71
• Mol File: 71482-65-0.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Propanone, 1-chloro-3-(trimethylsilyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propanone, 1-chloro-3-(trimethylsilyl)-(71482-65-0)
• EPA Substance Registry System: 2-Propanone, 1-chloro-3-(trimethylsilyl)-(71482-65-0)

Safety Data

• Hazardous Substances Data: 71482-65-0(Hazardous Substances Data)

Upstream product

• 71482-53-6 1-diazo-3-trimethylsilyl-2-propanone 
• 13170-43-9 (trimethylsilyl)methylmagnesium chloride 
• 79-04-9 chloroacetyl chloride 
• 541-88-8 Chloroacetic anhydride 
• 2344-80-1 Chloromethyltrimethylsilane 
• 2345-38-2 trimethylsilylacetic acid 
• 63877-23-6 (trimethylsilyl)acetyl chloride 

Downstream Products

• 76634-95-2 3-chloro-2-(trimethylsilyloxy)prop-1-ene 
• 59021-31-7 2-trimethylsilyloxy-3-phenyl-1-propene 
• 105302-65-6 {Pt(η3-CH2C(O)CH2)(PPh3)2} 

Relevant articles and documents

Selective formation of alkenes from trimethylsilylmethyl ketones and from acylsilanes

Trimethylsilylmethyl ketones, readily available from acyl chlorides, undergo a Reformatsky-Peterson reaction sequence to give 3-alkenoates regioselectively.Acylsilanes, however, react with either zinc ester enolates or trimethylsilylmethylmagnesium chloride to give the corresponding tertiary alcohols which, depending on their structure, spontaneously undergo either elimination or a Brook rearrangement-Peterson olefination sequence.These reactions allow the selective formation of vinylsilanes.