71559-40-5

Basic information

• Product Name: t-1-iodo-c-2-isothiocyanato-r-1-trimethylsilylcyclohexane
• CAS NO: 71559-40-5
• Molecular Weight: 339.316
• Mol File: 71559-40-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: t-1-iodo-c-2-isothiocyanato-r-1-trimethylsilylcyclohexane(CAS DataBase Reference)
• NIST Chemistry Reference: t-1-iodo-c-2-isothiocyanato-r-1-trimethylsilylcyclohexane(71559-40-5)
• EPA Substance Registry System: t-1-iodo-c-2-isothiocyanato-r-1-trimethylsilylcyclohexane(71559-40-5)

Safety Data

• Hazardous Substances Data: 71559-40-5(Hazardous Substances Data)

Upstream product

• 17874-17-8 cyclohex-1-enyl-trimethyl-silane 
• 556-65-0 lithium thiocyanate 

Relevant articles and documents

ADDITION OF IODINE-BASED ELECTROPHILIC REAGENTS TO SOME VINYLSILANES

The addition of some iodine-based electrophilic reagents to the cyclic vinylsilanes (1) and (4, R=But, R1=H) and (4, R=H, R1=OMe) occurs with high regio- and stereo-specificity to give (2, X=OMe, N3 and NCS) and (5, R=But, R1=H, X=OMe and N3) and (5, R=H, R1=OMe, X=OMe).Similar additions to 2-trimethylsilylhept-1-ene (6) are less efficient and occur with lower regioselectivity.Some of the adducts (2) and (5) have been transformed into functionalised organosilanes.Compounds (10, X=OMe, N3, and NCS) and (12)-(15) are thereby obtained.