715654-56-1

Basic information

• Product Name: (3aR,7aR)-1,3-Dimethyl-2-(2-methylsulfanyl-phenyl)-octahydro-benzo[1,3,2]diazaphosphole 2-oxide
• Synonyms: (3aR,7aR)-1,3-Dimethyl-2-(2-methylsulfanyl-phenyl)-octahydro-benzo[1,3,2]diazaphosphole 2-oxide
• CAS NO: 715654-56-1
• Molecular Weight: 310.4
• Mol File: 715654-56-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3aR,7aR)-1,3-Dimethyl-2-(2-methylsulfanyl-phenyl)-octahydro-benzo[1,3,2]diazaphosphole 2-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: (3aR,7aR)-1,3-Dimethyl-2-(2-methylsulfanyl-phenyl)-octahydro-benzo[1,3,2]diazaphosphole 2-oxide(715654-56-1)
• EPA Substance Registry System: (3aR,7aR)-1,3-Dimethyl-2-(2-methylsulfanyl-phenyl)-octahydro-benzo[1,3,2]diazaphosphole 2-oxide(715654-56-1)

Safety Data

• Hazardous Substances Data: 715654-56-1(Hazardous Substances Data)

Upstream product

• 137943-77-2 (3aR,7aR)-2-chloro-1,3-dimethyloctahydro-1H-1,3,2-benzodiazaphosphole 2-oxide 
• 74-88-4 methyl iodide 
• 715654-55-0 (3aR,7aR)-1,3-Dimethyl-2-phenylsulfanyl-octahydro-benzo[1,3,2]diazaphosphole 2-oxide 

Relevant articles and documents

Synthesis of chiral ortho-thio-substituted phenyl phosphonodiamidates via a P-S to P-C rearrangement

The ortho-lithiation of a phenyl phosphorodiamidothioate derived from an enantiopure C2-symmetric diamine is studied. It is shown that the migration of the diaminophosphoryl group from sulfur to carbon, leading to an ortho-sulfanylated phenyl phosphonodiamidate, only occurs in the presence of an alkylating agent or a Lewis acid as BF3·Et2O. The influence of the chiral diaminophosphoryl group on the stereoselectivity of the oxidation of the ortho-sulfanyl or alkylsulfanyl group is also examined.