71581-10-7

Basic information

• Product Name: trans-bis(triphenylphosphino)Pt(CF₃)Cl
• CAS NO: 71581-10-7
• Molecular Weight: 824.121
• Mol File: 71581-10-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: trans-bis(triphenylphosphino)Pt(CF₃)Cl(CAS DataBase Reference)
• NIST Chemistry Reference: trans-bis(triphenylphosphino)Pt(CF₃)Cl(71581-10-7)
• EPA Substance Registry System: trans-bis(triphenylphosphino)Pt(CF₃)Cl(71581-10-7)

Safety Data

• Hazardous Substances Data: 71581-10-7(Hazardous Substances Data)

Upstream product

• 107-07-3 2-chloro-ethanol 
• 154648-51-8 Pt(CF₃)(NCC₆H₄CH₃)[P(C₆H₅)3]2⁽¹⁺⁾*BF₄^(1-)=[Pt(CF₃)(NCC₆H₄CH₃)P₂(C₆H₅)6]BF₄ 
• 154648-45-0 Pt(CF₃)(NCC(CH₃)3)[P(C₆H₅)3]2⁽¹⁺⁾*BF₄^(1-)=[Pt(CF₃)(NCC(CH₃)3)P₂(C₆H₅)6]BF₄ 
• 176900-85-9 Pt(CF₃)(P(C₆H₅)3)2(NCCH₂CH(CO₂CH₃)NHCOOCH₂C₆H₅)⁽¹⁺⁾*BF₄^(1-)=[Pt(CF₃)(P(C₆H₅)3)2(NCCH₂CH(CO₂CH₃)NHCOOCH₂C₆H₅)]BF₄ 
• 64933-32-0 trans-PtBr(CF₃)(P(C₆H₅)3)2 
• 529-19-1 2-Methylbenzonitrile 
• 627-30-5 1-chloro-3-hydroxypropane 

Downstream Products

• 203129-37-7 trans-[Pt(CC(p-tolyl))(CO)(PPh₃)2][BF₄] 
• 125892-86-6 trans-[Pt(CF₃)(PPh₃)2(Me₂CO)]BF₄ 
• 119296-36-5 (o-bis(diphenylphosphino)benzene)Pt(CF₃)Cl 
• 119296-49-0 (N-benzyl-3,4-bis(diphenylphosphino)pyrrolidine)Pt(CF₃)Cl 
• 119296-26-3 {(bis(diphenylphosphino)methane)Pt(CF₃)P(C₆H₅)3}OH 
• 119296-33-2 (1,3-bis(diphenylphosphino)propane)Pt(CF₃)Cl 
• 52595-94-5 dichloro(bis(diphenylphosphino)methane)platinum(II) 
• 119296-30-9 (bis(diphenylphosphino)methane)Pt(CF₃)Cl 
• 13517-35-6 tris(triphenylphosphine)platinum⁽⁰⁾ 

Relevant articles and documents

Coordination and reactivity of benzyloxycarbonyl-Ala(CN)-OR (R = H, CH3) in complexes of platinum (II)

The conversion of a nitrile to an oxazoline group in an amino acid side chain promoted by platinum(II) was investigated. While benzyloxycarbonyl-β-cyano-alanine (Z-Ala(CN)-OH) did not give any evidence of coordination of the nitrile group to Pt(II) in different complexes, the corresponding methyl ester Z-Ala(CN)-OCH3 readily afforded the Pt(II)-nitrile complex trans-[Pt(CF3){Z-Ala(CN)-OCH3}(PPh3) 2][BF4] in good yield by reaction with the cationic derivative trans-[Pt(CF3)(PPh3)2(solv)][BF4] (solv = CH2Cl2). The reactivity of the CN group in the complex trans-[Pt(CF3){Z-Ala(CN)OCH3}(PPh3) 2] [BF4] with ClCH2CH2O-to form the oxazoline ligand 2 was examined. The presence of the oxazoline ring in the final products was evidenced by IR, 1H and 13C NMR data and confirmed by FAB and MALDI mass spectra, but its isolation was hampered by the cleavage of the oxazoline ring under the chromatographic conditions applied.