71659-62-6Relevant articles and documents
One approach to cyclic carbonates via a three-component cyclization of phenacyl bromide, CO2, and aldehyde
Yan, Peng,Tan, Xueqin,Jing, Huanwang,Duan, Shuhui,Wang, Xiaoxuan,Liu, Zhongli
experimental part, p. 2459 - 2464 (2011/05/14)
A three-component cyclization reaction was designed for synthesizing cyclic carbonates in a single operation from phenacyl bromide, CO2, and aldehyde in the presence of lithium diisopropylamide (LDA). These novel reactions were achieved under extremely mild conditions to generate the target products in moderate to good yields within 10 min.
Photochemistry of Aromatic α,β-Epoxy Ketones. Substituent Effects on Oxirane Ring-Opening and Related Ylide Behavior
Kumar, C. V.,Ramaiah, D.,Das, P. K.,George, M. V.
, p. 2818 - 2825 (2007/10/02)
Upon 337.1-nm laser excitation, chalcone epoxides containing donor/acceptor substituents at para positions of phenyl and benzoyl groups undergo triplet-mediated ring opening to carbonyl ylides observable by broad absorption spectra (λmaxY=520-600 nm, εmaxY (13-27) x 103 M-1 cm-1 in benzene) on a microsecond time scale (τY=0.4-24 μs in benzene).The short-lived, carbonyl-type triplets (τT=0.8-100 ns) giving rise to ylides are monitored in some cases by direct transient absorption on a nanosecond time scale and, for all systems, are probed by quenching studies with 1-methylnaphthalene and 2,5-dimethyl-2,4-hexadiene.Substituent effects on ylide absorption maxima, ylide decay kinetics, reactivity toward dipolarophiles and methanol, and precursor triplet lifetimes are discussed in the light of charge delocalization in dipolar structures, variation in HOMO/LUMO energies, complexity of thermal processes contributing to ylide decay, and energy gap between an ylide triplet and its triplet carbonyl precursor (ring closed).
