71740-68-6

Basic information

• Product Name: N,N-bis<2,4,6-tri(tert-butyl)phenyl>sulfur diimide
• Synonyms: N,N-bis<2,4,6-tri(tert-butyl)phenyl>sulfur diimide
• CAS NO: 71740-68-6
• Molecular Weight: 550.936
• Mol File: 71740-68-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N,N-bis<2,4,6-tri(tert-butyl)phenyl>sulfur diimide(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-bis<2,4,6-tri(tert-butyl)phenyl>sulfur diimide(71740-68-6)
• EPA Substance Registry System: N,N-bis<2,4,6-tri(tert-butyl)phenyl>sulfur diimide(71740-68-6)

Safety Data

• Hazardous Substances Data: 71740-68-6(Hazardous Substances Data)

Upstream product

• 58949-87-4 2,4,6-tri-tert-butyl-7,8,9-dithiazabicyclo<4.3.0>nona-1(9),2,4-triene 
• 603-35-0 triphenylphosphine 

Relevant articles and documents

Chemistry of N-Thiosulfinylanilines. V. Reactions of N-Thiosulfinylanilines with Nucleophilic Reagents

2,4-Di-t-butyl-6-methyl-N-(thiosulfinyl)aniline (1) gave 2,4-di-t-butyl-6-methylaniline in the reactions with such reagents as alkylamines, thiourea, butyllithium, alkylmagnesium halides, 1-(1-pyrrolidinyl)cyclopentene, and hydrogen sulfide.Triphenylphosphine reacted with 1 to give (2,4-di-t-butyl-6-methylphenylimino)triphenylphosphorane and bis(2,4-di-t-butyl-6-methylphenyl)sulfur diimide.Reaction of triphenylphosphine with 2,4,6-tri-t-butyl-7,8-dithia-9-azabicyclonona-2,4,9-triene afforded 2,4,6-tri-t-butylaniline, bis(2,4,6-tri-t-butylphenyl)sulfur diimide, and 2,4,6-tri-t-butyl-N-sulfinylaniline (7).The sulfur diimide was considered to be formed via intermediary 2,4,6-tri-t-butylthionitrosobenzene, which was trapped by oxygen to give the N-sulfinyl derivative 7.