7175-96-4Relevant articles and documents
Preparation method of 2,6-ditert-butyl phenol salt
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Paragraph 0013-0015; 0018-0019; 0021-0022, (2018/04/01)
The invention provides a preparation method of 2,6-ditert-butyl phenol salt. The preparation method comprises the following steps: carrying out reflux dehydration reaction on 2,6-ditert-butyl phenol and an alkali metal compound in a molar ratio of (1 to 1)-(1 to 1.4) in a benzene solvent under the protection of inert gas; and after the reaction is finished, cooling and filtering under the protection of inert gas, and carrying out vacuum drying, so as to obtain an off-white solid product, namely the 2,6-ditert-butyl phenol salt. According to the preparation method, by carrying out reflux dehydration by virtue of the benzene solvent, the reaction process is accelerated, the reaction time is shortened, and the synthetic efficiency of the 2,6-ditert-butyl phenol salt is improved; the benzene solvent is capable of taking away unreacted raw materials and generated impurities in a post-treatment filtration process, so that the product purity is increased; the prepared 2,6-ditert-butyl phenol salt is an off-white product, high in quality and wide in use range; and the protection of inert gas is implemented in the reaction process and the post-treatment process, so that air can be effectively isolated, the production of byproducts is reduced, and the yield of the 2,6-ditert-butyl phenol salt is increased.
Lithium and Sodium 2,6-Di-tert-butylphenoxides and the Crystal and Molecular Structure of t2-2,6)(OEt)2>2
Cetinkaya, B.,Guemruekcue, I,Lappert, M. F.,Atwood, J. L.,Shakir, R.
, p. 2086 - 2088 (2007/10/02)
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