71787-52-5

Basic information

• Product Name: Benzenemethanol, 3-nitro-a-2-propenyl-
• CAS NO: 71787-52-5
• Molecular Formula: C10H11NO3
• Molecular Weight: 193.202
• Mol File: 71787-52-5.mol
• Article Data: 37

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, 3-nitro-a-2-propenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 3-nitro-a-2-propenyl-(71787-52-5)
• EPA Substance Registry System: Benzenemethanol, 3-nitro-a-2-propenyl-(71787-52-5)

Safety Data

• Hazardous Substances Data: 71787-52-5(Hazardous Substances Data)

Upstream product

• 99-61-6 3-nitro-benzaldehyde 
• 762-72-1 allyl-trimethyl-silane 
• 106-95-6 allyl bromide 
• 107-05-1 3-chloroprop-1-ene 
• 591-87-7 Allyl acetate 
• 1200328-33-1 1-nitro-3-[1-[(trimethylsilyl)oxy]-3-buten-1-yl]benzene 
• 7393-43-3 tetraallyl tin 
• 1730-25-2 allylmagnesium bromide 
• 29949-19-7 1,1-diacetoxy-1-(3-nitrophenyl)methane 
• 24850-33-7 allyltributylstanane 
• 2551-83-9 allyltrimethoxysilane 
• 2550-04-1 allyltriethoxysilane 

Downstream Products

• 1023294-91-8 1-(3-nitrophenyl)but-3-en-1-one 
• 1160487-98-8 O-(1-(3-nitrophenyl)but-3-enyl)hydroxylamine 
• 129277-18-5 4-hydroxy-4-(3-nitrophenyl)-butan-2-one 
• 946-68-9 (E)-4-(3-nitrophenyl)but-3-en-2-one 
• 1620206-36-1 (E)-N-(1-bromo-4-(3-nitrophenyl)but-3-en-2-yl)-2,2,2-trichloroacetamide 
• 1620206-53-2 (E)-4-(3-nitrostyryl)-2-(trichloromethyl)-4,5-dihydro-oxazole 
• 1620206-18-9 C₁₂H₁₁Cl₃N₂O₃ 

Relevant articles and documents

Copper-catalyzed radical oxyallylation of olefins for the construction of alkene-containing isoxazolines

A radical-mediated approach to alkene oxyallylation using allylic oximes is described. The reaction proceeds under copper-catalytic redox-neutral conditions and tolerates various functional groups. This protocol thus enables the synthesis of structurally valuable isoxazolines and the introduction of a versatile olefin motif in a single step.

Copper-Impregnated Magnesium-Lanthanum Mixed Oxide: A Reusable Heterogeneous Catalyst for Allylation of Aldehydes and Ketones

Copper-impregnated magnesium-lanthanum mixed oxide [Cu(II)/Mg?La] was used as catalyst in synthesis of homoallylic alcohols from aldehydes and ketones using allyltributylstannane as the allylating source. The present protocol provides a great application

Active bismuth mediated allylation of carbonyls/N-tosyl aldimines and propargylation of aldehydes in water

Abstract: Active bismuth is synthesized by the chemical reduction of bismuth trichloride using freshly prepared sodium stannite solution as the reducing agent at room temperature. The as-synthesized active bismuth is applied as a reagent for the synthesis of homoallyl alcohol/homopropargyl alcohol from allyl bromide/propargyl bromide and carbonyl compounds in water at 50°C. The homoallyl amines are also synthesized from N-tosyl aldimines and allyl bromide using active bismuth reagent in good yields. No assistance of organic co-solvent, co-reagent, phase transfer catalyst or inert atmosphere is required for this reaction. The waste bismuth material obtained after the completion of the organic reaction can be reduced to active bismuth by sodium stannite solution and successfully reused for mediating the allylation of aldehydes. Graphical Abstract:: Synopsis Active bismuth mediated allylation/crotylation of aldehydes is developed in water to get homoallyl alcohols. The method is also applied for the allylation of N-tosyl aldimines and propargylation of aldehydes in water to achieve the homoallyl amines and homopropargyl alcohols, respectively. The reactions do not require the assistance of organic co-solvent, co-reagent, phase transfer catalyst or inert atmosphere.[Figure not available: see fulltext.].