718-36-5

Basic information

• Product Name: P-NITROBENZYLIDENE TERT-BUTYLAMINE
• Synonyms: 2-Methyl-N-[(E)-(4-nitrophenyl)methylidene]-2-propanamine;tert-Butyl-(4-nitro-benzylidene)-amine;N-tert-butyl-1-(4-nitrophenyl)methanimine;TIMTEC-BB SBB007794;P-NITROBENZYLIDENE TERT-BUTYLAMINE
• CAS NO: 718-36-5
• Molecular Formula: C₁₁H₁₄N₂O₂
• Molecular Weight: 206.24
• Mol File: 718-36-5.mol
• Article Data: 14

Chemical Properties

• Boiling Point: 312.3°C at 760 mmHg
• Flash Point: 142.7°C
• Appearance: /
• Density: 1.06g/cm³
• Vapor Pressure: 0.000978mmHg at 25°C
• Refractive Index: 1.524
• CAS DataBase Reference: P-NITROBENZYLIDENE TERT-BUTYLAMINE(CAS DataBase Reference)
• NIST Chemistry Reference: P-NITROBENZYLIDENE TERT-BUTYLAMINE(718-36-5)
• EPA Substance Registry System: P-NITROBENZYLIDENE TERT-BUTYLAMINE(718-36-5)

Safety Data

• Hazardous Substances Data: 718-36-5(Hazardous Substances Data)

Usage

General Description

P-Nitrobenzylidene tert-butylamine is a chemical compound with the molecular formula C14H18N2O2. It is used as a reagent in organic synthesis and as a precursor for the preparation of various other chemical compounds. P-NITROBENZYLIDENE TERT-BUTYLAMINE is yellow in color and is known to be sensitive to air and light. It is mainly used in the pharmaceutical industry for the synthesis of various drugs and in the production of dyes and pigments. P-Nitrobenzylidene tert-butylamine is a versatile and important chemical in the field of organic chemistry and has numerous applications in different industries.

InChI:InChI=1/C11H14N2O2/c1-11(2,3)12-8-9-4-6-10(7-5-9)13(14)15/h4-8H,1-3H3/b12-8+

Upstream product

• 555-16-8 4-nitrobenzaldehdye 
• 75-64-9 tert-butylamine 
• 576-26-1 2.6-dimethylphenol 
• 26378-36-9 2-tert-butyl-3-(4-nitrophenyl)-1,2-oxaziridine 
• 2078-54-8 2,6-diisopropylphenol 
• 3489-67-6 N-(t-butyl)-N-p-nitrobenzylamine 
• 110079-36-2 C₁₁H₁₅ClN₂O₂ 
• 75-18-3 dimethylsulfide 

Downstream Products

• 18885-93-3 4-tert-butyl-3-methyl-5-(4-nitro-phenyl)-4,5-dihydro-[1,2,4]oxadiazole 
• 26378-36-9 2-tert-butyl-3-(4-nitrophenyl)-1,2-oxaziridine 
• 153164-05-7 (E)-7-p-nitrobenzylidene-2H,6H-naphtho<1,8-b,c>furan-2,6-dione 
• 42498-30-6 N-tert-butyl-4-nitrobenzamide 
• 40117-28-0 N-(4-methoxy)benzylidene-t-butylamine N-oxide 
• 3585-88-4 N-tert-butyl-α-(4-nitrophenyl)nitrone 
• 3489-67-6 N-(t-butyl)-N-p-nitrobenzylamine 
• 131479-98-6 diethyl t-butylamino(4-nitrophenyl)methanephosphonate 
• 26378-36-9 (3S)-trans-2-tert-butyl-3-(4-nitro-phenyl)-oxaziridine 
• 527-61-7 2,6-dimethyl-1,4-benzoquinone 
• 1988-11-0 2,6-diisopropyl-1,4-benzoquinone 
• 555-16-8 4-nitrobenzaldehdye 
• 88343-92-4 2,6-Di-tert-butyl-4-[hydroxy-(4-nitro-phenyl)-methyl]-phenol 
• 77621-69-3 C₃₅H₄₇NO₄ 

Relevant articles and documents

One-Pot Synthesis of Diazirines and 15N2-Diazirines from Ketones, Aldehydes and Derivatives: Development and Mechanistic Insight

Broad scope one-pot diazirine synthesis strategies have been developed using two different oxidants depending on the nature of the starting material. In all cases, an inexpensive commercial solution of ammonia (NH3) in methanol (MeOH) was emplo

Carbonylation Access to Phthalimides Using Self-Sufficient Directing Group and Nucleophile

Herein we report a novel palladium-catalyzed oxidative carbonylation reaction for the synthesis of phthalimides with high atom- and step-economy. In our strategy, the imine and H2O, which are generated in situ from the condensation of aldehyde and amine, serve as self-sufficient directing group and nucleophile, respectively. This method provides rapid access to phthalimides starting from readily available materials in a one-pot manner. Various phthalimide derivatives are constructed efficiently, including medicinally and biologically active phthalimide-containing compounds.

Hydrogen peroxide/dimethyl carbonate: A green system for epoxidation of: N -alkylimines and N -sulfonylimines. One-pot synthesis of N -alkyloxaziridines from N -alkylamines and (hetero)aromatic aldehydes

A green method for epoxidation of imines using an environmentally benign oxidant system, H2O2/dimethyl carbonate, was developed. N-Alkyloxaziridines were prepared in high yields from N-alkylamines and (hetero)aromatic aldehydes in one-pot fashion, whereas N-sulfonyloxaziridines have been prepared by using the same oxidant system and 5 mol% of Zn(OAc)2·2H2O as catalyst.