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718-71-8

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718-71-8 Usage

Chemical Properties

Yellowish Oil

Uses

Ethyl Cyanoethylphenylacetate (cas# 718-71-8) is a compound useful in organic synthesis.

Check Digit Verification of cas no

The CAS Registry Mumber 718-71-8 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 7,1 and 8 respectively; the second part has 2 digits, 7 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 718-71:
(5*7)+(4*1)+(3*8)+(2*7)+(1*1)=78
78 % 10 = 8
So 718-71-8 is a valid CAS Registry Number.
InChI:InChI=1/C13H15NO2/c1-3-13(10-14,12(15)16-4-2)11-8-6-5-7-9-11/h5-9H,3-4H2,1-2H3

718-71-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name ethyl 2-cyano-2-phenylbutanoate

1.2 Other means of identification

Product number -
Other names cyano-ethyl-phenyl-acetic acid ethyl ester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:718-71-8 SDS

718-71-8Relevant articles and documents

Tert-Butoxide-Mediated Arylation of 2-Substituted Cyanoacetates with Diaryliodonium Salts

Qian, Xiaofei,Han, Jianwei,Wang, Limin

, p. 940 - 946 (2016/04/05)

A transition metal-free direct arylation of 2-substituted cyanoacetates with diaryliodonium salts was developed. With this approach, a wide range of α-tolunitrile derivatives has been synthesized in good to excellent yields of 45-92%. Furthermore, the practicability of this approach is further manifested in the synthesis of a related bioactive agent of glutarimide.

Nucleophile generation via decarboxylation: Asymmetric construction of contiguous trisubstituted and quaternary stereocenters through a Cu(I)-catalyzed decarboxylative mannich-type reaction

Yin, Liang,Kanai, Motomu,Shibasaki, Masakatsu

supporting information; experimental part, p. 9610 - 9611 (2011/03/19)

(Chemical Equation Presented) The first catalytic asymmetric decarboxylative Mannich-type reaction between aldimines and cyanocarboxylic acids was developed. α,α,β-Trisubstituted β-amino nitriles containing contiguous trisubstituted and all-carbon quatern

Selective Mono-methylation of Arylacetonitriles and Methyl Arylacetates by Dimethyl Carbonate

Selva, Maurizio,Marques, Carlos Alberto,Tundo, Pietro

, p. 1323 - 1328 (2007/10/02)

Both arylacetonitriles and methyl arylacetates react with dimethyl carbonate (DMC) (20 molar excess) at 180 - 200 deg C in the presence of K2CO3 to produce monomethylated 2-arylpropionitriles and methyl 2-arylpropionates, respectively, with a selectivity >99.5percent.The reaction, with wide application, proceeds by DMC acting as a methoxycarbonylating agent towards the ArCH-X anion (X = CN, CO2Me) and as a methylating agent to ArC-(CO2Me)X.DMC also proved to be the best solvent for such reactions.

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