71866-86-9Relevant articles and documents
Nanosized Molecular Propellers by Cyclodehydrogenation of Polyphenylene Dendrimers
Simpson, Christopher D.,Mattersteig, Gunter,Martin, Kai,Gherghel, Lileta,Bauer, Roland E.,Raeder, Hans Joachim,Muellen, Klaus
, p. 3139 - 3147 (2004)
In a polymer analogous approach, large dendritic oligophenylenes containing benzene and tetraphenylmethane cores are transformed via oxidative cyclodehydrogenation to novel propeller-shaped molecules with large polycyclic aromatic hydrocarbon units as "bl
Preparation method and application of porphyrin polymer
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Paragraph 0078-0086, (2020/08/30)
The invention belongs to the field of photo-Fenton catalysts, and particularly relates to a preparation method and application of a porphyrin polymer. A photo-Fenton catalyst used at present generallyneeds to be subjected to a catalytic reaction under ultraviolet light and acidic conditions, ultraviolet light irradiation and acid liquor need to be added for treatment, metal ion leaching can be accompanied in the catalytic process, and the environment is remarkably influenced. The invention provides a porous organic polymer based on metalloporphyrin. FePPOP-1 is synthesized through a Sonogashira cross coupling reaction of FeTBrPP and TEPB. The polymer has good stability, and compared with a traditional Fenton reaction, FePPOP-1 can still effectively degrade MB under the neutral condition that the pH value is equal to 7, and leaching of iron ions does not exist in the reaction process. The research result provides a research direction for the application of the metalloporphyrin porous organic polymer in the photo-Fenton catalyst.
Clicked isoreticular metal-organic frameworks and their high performance in the selective capture and separation of large organic molecules
Li, Pei-Zhou,Wang, Xiao-Jun,Tan, Si Yu,Ang, Chung Yen,Chen, Hongzhong,Liu, Jia,Zou, Ruqiang,Zhao, Yanli
supporting information, p. 12748 - 12752 (2015/10/28)
Three highly porous metal-organic frameworks (MOFs) with a uniform rht-type topological network but hierarchical pores were successfully constructed by the assembly of triazole-containing dendritic hexacarboxylate ligands with ZnII ions. These