71964-06-2

Basic information

• Product Name: Benzene, 1-[(1,2-dimethyl-1-propenyl)sulfonyl]-4-methyl-
• CAS NO: 71964-06-2
• Molecular Formula: C12H16O2S
• Molecular Weight: 224.324
• Mol File: 71964-06-2.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzene, 1-[(1,2-dimethyl-1-propenyl)sulfonyl]-4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-[(1,2-dimethyl-1-propenyl)sulfonyl]-4-methyl-(71964-06-2)
• EPA Substance Registry System: Benzene, 1-[(1,2-dimethyl-1-propenyl)sulfonyl]-4-methyl-(71964-06-2)

Safety Data

• Hazardous Substances Data: 71964-06-2(Hazardous Substances Data)

Upstream product

• 513-35-9 2-methyl-but-2-ene 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 98-59-9 p-toluenesulfonyl chloride 
• 7569-34-8 ethyl p-tolyl sulfone 
• 14799-12-3 2-methyl-3-(toluene-4-sulfonyl)-butan-2-ol 
• 3017-70-7 2-bromo-3-methylbut-2-ene 
• 1576-35-8 toluene-4-sulfonic acid hydrazide 
• 1950-78-3 p-toluenesulfonyl iodide 
• 7257-26-3 sodium p-toluenesulfinate tetrahydrate 
• 105465-57-4 1-[1,1-Dimethyl-2-(toluene-4-sulfonyl)-propyl]-pyrrolidine 
• 71963-98-9 2-iodo-2-methyl-3-tosylbutane 
• 67275-03-0 ethyl 2,3-dimethyl-3-nitro-2-tosylbutanoate 

Downstream Products

• 1430110-94-3 (E)-1-(4,5-dimethylhexa-3,5-dien-1-yl)-4-methoxybenzene 
• 1430110-97-6 (Z)-1-(4,5-dimethylhexa-3,5-dien-1-yl)-4-methoxybenzene 

Relevant articles and documents

CONVENIENT METHODS FOR THE PREPARATION OF VINYLIC AND ALLYLIC SULFONES FROM ALKENES

1 or 2-p-Toluenesulfonyl(=tosyl)-1-alkenes were regioselectively prepared from 1-alkenes via iodosulfonization or sulfonylmercuration, respectively.Conversion of 1-tosyl-1-alkenes to the corresponding allylic sulfones, 1-tosyl-2-alkenes, was achieved by t

Coupling reaction of magnesium alkylidene carbenoids with α-sulfonylallyllithiums: An efficient route to multi-substituted vinylallenes

A variety of vinylallenes were successfully synthesized from 1-chlorovinyl p-tolyl sulfoxides and allyl or vinyl sulfones. Allyl and vinyl sulfones served as α-sulfonylallyllithium sources were prepared from carbonyl compounds in three or four steps in good overall yields. The coupling reaction of α-sulfonylallyllithiums with magnesium alkylidene carbenoids, which were generated from 1-chlorovinyl p-tolyl sulfoxides and isopropylmagnesium chloride, afforded multi-substituted vinylallenes in up to 88% yield. Georg Thieme Verlag KG Stuttgart · New York.

A CONVENIENT METHOD FOR THE PREPARATION OF α-ALKYLATED VINYLIC SULFONES AND THEIR CONVERSION TO ALLYLIC SULFONES

2-Pyrrolidinoalkyl p-tolyl sulfones, which were readily available by the addition of pyrrolidine to vinylic or allylic sulfones, were converted to the corresponding α-alkylated vinylic sulfones through α-alkylation followed by elimination of pyrrolidino g