71996-32-2Relevant articles and documents
Dibenzothiophenesulfilimines: A Convenient Approach to Intermolecular Rhodium-Catalysed C?H Amidation
Antoni, Patrick W.,Mackenroth, Alexandra V.,Mulks, Florian F.,Rudolph, Matthias,Helmchen, Günter,Hashmi, A. Stephen K.
supporting information, p. 8235 - 8238 (2020/06/17)
A sulfilimine-based Group 9 transition-metal-catalysed C?H amidation procedure is reported. Dibenzothiophene-based sulfilimines were shown to constitute a class of novel amidation reagents which enable the transfer of a wide range of N-sulfonyl and N-acyl
Generation of nitrene by the photolysis of N-substituted iminodibenzothiophene
Morita, Hiroyuki,Tatami, Atsushi,Maeda, Tetsuo,Byung, Ju Kim,Kawashima, Wataru,Yoshimura, Toshiaki,Abe, Hitoshi,Akasaka, Takeshi
body text, p. 7159 - 7163 (2009/04/18)
(Chemical Equation Presented) To evaluate the ability of dibenzothiophene N-substituted sulfilimines as photochemical nitrene sources, their photolyses in the presence of several trapping reagents, such as sulfides, olefins, and phosphorus compounds, were performed. In the reactions, the corresponding imino-transfer compounds, namely sulfilimines, aziridines, and iminophosphoranes, were formed in good yields, indicating dibenzothiophene N-tosyl and N-acylsulfilimines have a potent nature as nitrogen sources.
POLAROGRAPHIC STUDY OF STRUCTURE-PROPERTIES RELATIONSHIP OF p-TOSYL SULFILIMINES
Svoronos, Paris,Horak, Vaclav,Zuman, Peter
, p. 139 - 148 (2007/10/02)
A structure-reactivity relationship for a series of eight N-p-tosyl sulfilimines and five related sulfoxides is investigated by polarographic reduction of the S-N and S-O bonds respectively.Conjugation of the tricoordinated sulfur is the dominant factor t