72035-56-4

Basic information

• Product Name: 5,5-dimethyl-3-phenoxycyclohex-2-en-1-one
• Synonyms: 5,5-dimethyl-3-phenoxycyclohex-2-en-1-one
• CAS NO: 72035-56-4
• Molecular Weight: 216.28
• Mol File: 72035-56-4.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 5,5-dimethyl-3-phenoxycyclohex-2-en-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 5,5-dimethyl-3-phenoxycyclohex-2-en-1-one(72035-56-4)
• EPA Substance Registry System: 5,5-dimethyl-3-phenoxycyclohex-2-en-1-one(72035-56-4)

Safety Data

• Hazardous Substances Data: 72035-56-4(Hazardous Substances Data)

Upstream product

• 126-81-8 dimedone 
• 2058-74-4 1-methyl-1H-indole-2,3-dione 
• 88284-48-4 2-(trimethylsilyl)phenyl trifluoromethanesulfonate 
• 35024-12-5 (4,4-dimethyl-2,6-dioxo-cyclohexyl)-phenyl-iodonium betaine 
• 3471-13-4 dimedone 
• 83566-44-3 tetraphenylbismuth 4-methylbenzenesulfonate 
• 83566-43-2 tetraphenyl-bismuth trifluoroacetate 
• 83566-45-4 tetraphenylbismuth trifluoromethanesulphonate 
• 94569-94-5 2-iodo-5,5-dimethyl-3-phenoxycyclohex-2-en-1-one 
• 140-88-5 ethyl acrylate 
• 13271-49-3 3-bromo-5,5-dimethlycyclohex-2-en-1-one 
• 108-95-2 phenol 
• 17530-69-7 3-chloro-5,5-dimethylcyclohex-2-en-1-one 
• 79169-56-5 tetraphenylbismuthonium trifluoroacetate 

Downstream Products

• 72035-75-7 (E)-7,7-Dimethyl-9-phenoxy-7,10-dihydro-6H-benzocycloocten-5-one 
• 72035-67-7 (E)-7,7-Dimethyl-9-phenoxy-7,8-dihydro-6H-benzocycloocten-5-one 
• 72035-95-1 1-(2-Methyl-allyl)-3-phenoxy-naphthalene 
• 72035-85-9 1-(2-Methyl-propenyl)-3-phenoxy-naphthalene 
• 77670-23-6 5,5-Dimethyl-3-(phenylthio)cyclohexanone 
• 4694-17-1 5,5-dimethlycyclohex-2-en-1-one 
• 96530-07-3 5,5-dimethyl-3-phenoxy-2-cyclohexenol 
• 128445-79-4 4,4-Dimethyl-6-phenoxy-7-oxa-bicyclo[4.1.0]heptan-2-one 
• 72035-62-2 2,2-Dimethyl-3-phenoxy-2,2a-dihydro-1H-cyclobuta[a]naphthalen-8b-ol 

Relevant articles and documents

One-pot synthesis of 3-substituted-3-hydroxyindolin-2-ones: three component coupling ofN-protected isatin, aryne precursor and 1,3-cyclodione under metal-free conditions

An aryne-based synthetic protocol has been developed for the synthesis of 3-substituted-3-hydroxy-indolin-2-ones. A wide variety of 3-hydroxyindolin-2-ones were synthesized in good yields under metal-free conditionsviathree component coupling ofN-protected isatin, aryne precursor, and 1,3-cyclodione. One of our synthesized compounds has been unambiguously confirmed by single crystal XRD analysis. Further, treating the synthesized 3-hydroxyindolin-2-one derivatives with an inorganic base at high temperature leads to an interestingo-arylated product of 1,3-cyclohexandione.

Copper-catalyzed regio- and stereoselective O-arylation of enolates

Copper-catalyzed O-arylation of enolates with diaryliodonium salts as arylating reagents was realized successfully. As important building blocks, β-aryloxy carbonyl compounds were obtained in up to 98% yield under mild conditions, and complete control of

Reduction of Vinylogous Thioesters with Lithium Aluminum Hydride. I. Reduction of β-Phenylthio-α,β-unsaturated Cyclic Ketones

5,5,Dimethyl-3-phenoxy-2-cyclohexenone (Ib) was reduced with lithium aluminum hydride (LAH) to give the 1,2-addition product (IIIa). 2-Methyl-3-phenoxy-2-cyclopentetnone (IIa) gave a mixture of the allyl alcohol (IVa) and 1,2-addition product (IVb).On the