7214-02-0

Basic information

• Product Name: 2-allyl-4-methylcyclohexanone
• Synonyms: 2-allyl-4-methylcyclohexanone
• CAS NO: 7214-02-0
• Molecular Weight: 152.236
• Mol File: 7214-02-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-allyl-4-methylcyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-allyl-4-methylcyclohexanone(7214-02-0)
• EPA Substance Registry System: 2-allyl-4-methylcyclohexanone(7214-02-0)

Safety Data

• Hazardous Substances Data: 7214-02-0(Hazardous Substances Data)

Upstream product

• 589-92-4 1-methylcyclohexan-4-one 
• 106-95-6 allyl bromide 
• 24420-11-9 1-allyl-pyrrolidine 
• 1471-03-0 allyl propyl ether 
• 591-87-7 Allyl acetate 

Downstream Products

• 110244-12-7 4-Methyl-2-[2-(5,6,7,8-tetrahydro-[2]naphthyl)-propyl]-cyclohexanol 
• 861372-15-8 4-methyl-2-propyl-cyclohexanone 
• 854717-71-8 4-methyl-2-(2-phenyl-propyl)-cyclohexanone 
• 854905-04-7 4-methyl-2-(2-p-tolyl-propyl)-cyclohexanone 
• 854718-46-0 2-[2-(2,5-dimethyl-phenyl)-propyl]-4-methyl-cyclohexanone 
• 7213-68-5 2-<2-<2>Naphthyl-propyl>-4-methyl-cyclohexanon 
• 7213-67-4 3,6-Dimethyl-tetraphen 
• 116530-92-8 Opt_.-inakt. 4-Hydroxy-1-methyl-3-propyl-cyclohexan 

Relevant articles and documents

Hydrogen-bond-activated palladium-catalyzed allylic alkylation via allylic alkyl ethers: Challenging leaving groups

C-O bond cleavage of allylic alkyl ether was realized in a Pd-catalyzed hydrogen-bond-activated allylic alkylation using only alcohol solvents. This procedure does not require any additives and proceeds with high regioselectivity. The applicability of this transformation to a variety of functionalized allylic ether substrates was also investigated. Furthermore, this methodology can be easily extended to the asymmetric synthesis of enantiopure products (99% ee).

Direct catalytic intermolecular α-allylic alkylation of aldehydes by combination of transition-metal and organocatalysis

(Chemical Equation Presented) All in the same pot together: The direct catalytic α-allylic alkylation of aldehydes and cyclic ketones is achieved by using a simple, unprecedented one-pot procedure. Transition-metal and enamine catalysis are combined so that α-allylic alkylated aldehydes and cyclic ketones are formed in high yield with a direct catalytic chemo- and regioselective method.