7214-55-3

Basic information

• Product Name: (E)-(4-nitrostyryl)(phenyl)sulfane
• Synonyms: (E)-(4-nitrostyryl)(phenyl)sulfane
• CAS NO: 7214-55-3
• Molecular Weight: 257.313
• Mol File: 7214-55-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-(4-nitrostyryl)(phenyl)sulfane(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(4-nitrostyryl)(phenyl)sulfane(7214-55-3)
• EPA Substance Registry System: (E)-(4-nitrostyryl)(phenyl)sulfane(7214-55-3)

Safety Data

• Hazardous Substances Data: 7214-55-3(Hazardous Substances Data)

Upstream product

• 18462-35-6 (E)-1-[2-bromovinyl]-4-nitrobenzene 
• 108-98-5 thiophenol 
• 586-78-7 para-nitrophenyl bromide 
• 1822-73-7 phenylthioethylene 
• 18462-34-5 (Z)-1-(2-bromovinyl)-4-nitrobenzene 
• 937-31-5 (4-Nitrophenyl)acetylene 

Downstream Products

• 18462-38-9 (E)-1-nitro-4-(2-(phenylsulfonyl)vinyl)benzene 

Relevant articles and documents

Stereoselective heck reactions with vinyl sulfoxides, sulfides and sulfones

We report the Heck cross-coupling of notoriously unreactive, but synthetically valuable olefins: vinyl sulfoxides, vinyl sulfones, and vinyl sulfides. Key findings include the importance of the sterically hindered (tri-tert-butyl)phosphine ligand and the unique effectiveness of triethylamine as the base. The method is general, E-selective, and can be used to synthesize disubstituted or trisubstituted olefins through simple adjustments of stoichiometry. Copyright