7214-56-4

Basic information

• Product Name: Benzene, [(2-phenylethenyl)thio]-, (Z)-
• CAS NO: 7214-56-4
• Molecular Formula: C14H12S
• Molecular Weight: 212.315
• Mol File: 7214-56-4.mol
• Article Data: 73

Chemical Properties

• CAS DataBase Reference: Benzene, [(2-phenylethenyl)thio]-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(2-phenylethenyl)thio]-, (Z)-(7214-56-4)
• EPA Substance Registry System: Benzene, [(2-phenylethenyl)thio]-, (Z)-(7214-56-4)

Safety Data

• Hazardous Substances Data: 7214-56-4(Hazardous Substances Data)

Upstream product

• 30536-77-7 <(phenylthio)(trimethylsilyl)methyl>lithium 
• 100-52-7 benzaldehyde 
• 82759-01-1 threo-1-Phenyl-2-phenylthio-2-(triphenylstannyl)ethanol 
• 82759-01-1 erythro-1-Phenyl-2-phenylthio-2-(triphenylstannyl)ethanol 
• 82759-03-3 erythro-1-Phenyl-2-phenylthio-2-(triphenylplumbyl)ethanol 
• 108-98-5 thiophenol 
• 536-74-3 phenylacetylene 
• 38066-16-9 diethyl [(phenylthio)methyl]phosphonate 
• 35460-31-2 (2-phenylsulfanylethynyl)benzene 
• 103-64-0 bromostyrene 
• 882-33-7 diphenyldisulfane 
• 622-25-3 1-(2-chlorovinyl)benzene 
• 80-17-1 benzenesufonyl hydrazide 
• 95391-86-9 (Z)-(phenylthio)ethenyl methyl selenide 

Downstream Products

• 645-49-8 cis-stilben 
• 103-30-0 (E)-1,2-diphenyl-ethene 
• 7214-53-1 (E)-[2-(phenylsulfanyl)vinyl]benzene 
• 40110-65-4 (+/-)_S-(Z)-2-phenyl-1-(phenylsulfinyl)ethene 
• 54648-37-2 3-(2,6-dichlorophenyl)-5-phenyl-isoxazole 
• 52920-46-4 Z-2-bromo-2-phenyl-1-(phenylsulfonyl)ethene 
• 98496-46-9 C₂₀H₁₆O₂S₂ 
• 98496-47-0 1-((Z)-2-Benzenesulfonyl-1-phenyl-vinylsulfanyl)-4-methyl-benzene 
• 98496-48-1 1-((Z)-2-Benzenesulfonyl-1-phenyl-vinylsulfanyl)-4-chloro-benzene 
• 98496-49-2 1-((Z)-2-Benzenesulfonyl-1-phenyl-vinylsulfanyl)-4-bromo-benzene 
• 98496-55-0 2-((Z)-2-Benzenesulfonyl-1-phenyl-vinylsulfanyl)-phenylamine 
• 98496-56-1 (Z)-α,β-bis(phenylsulfonyl)styrene 
• 98496-57-2 1-((Z)-2-Benzenesulfonyl-1-phenyl-ethenesulfonyl)-4-methyl-benzene 
• 98496-58-3 1-((Z)-2-Benzenesulfonyl-1-phenyl-ethenesulfonyl)-4-chloro-benzene 

Relevant articles and documents

Catalytic conversion of alkynes to α-vinyl sulfides mediated by carbene-linker-carbene (CXC) rhodium and iridium complexes

The catalytic activity of a set of mono- and bimetallic Rh(i) and Ir(i) complexes bearing carbene-linker-carbene (CXC) bis-triazolylidene ligands (with X = O, N) coordinated in a bridging or chelating fashion was evaluated in the hydrothiolation of alkyne

Sulfur?oxygen interaction-controlled (Z)-selectiveanti-Markovnikov vinyl sulfides

The sulfur oxygen (S?O) interaction was used herein to obtain (Z)-selectiveanti-Markovnikov vinyl sulfides from the addition of thiyl radicals to terminal alkynes. DFT calculations predicted that S?O interaction originated from the delocalization of the lone-pair of the carbonyl oxygen to the adjacent σ* orbital of the S atom of C-S.

Selectivity control in thiol-yne click reactions: Via visible light induced associative electron upconversion

An associative electron upconversion is proposed as a key step determining the selectivity of thiol-yne coupling. The developed synthetic approach provided an efficient tool to access a comprehensive range of products-four types of vinyl sulfides were prepared in high yields and selectivity. We report practically important transition-metal-free regioselective thiol-yne addition and formation of the demanding Markovnikov-type product by a radical photoredox process. The photochemical process was directly monitored by mass-spectrometry in a specially designed ESI-MS device with green laser excitation in the spray chamber. The proposed reaction mechanism is supported by experiments and DFT calculations. This journal is