721945-24-0Relevant articles and documents
Pd-Catalyzed Three-Component Reaction of Anilines, Ethyl Vinyl Ether, and Nitro-Paraffin: Assembly of β-Nitroamines
Ouyang, Lu,Zhan, Lingzhi,Li, Jianxiao,Zhang, Qiaoyu,Qi, Chaorong,Wu, Wanqing,Jiang, Huanfeng
, p. 550 - 553 (2018)
A novel palladium-catalyzed amination and nitration of ethyl vinyl ether for the construction of β-nitroamine derivatives under mild conditions has been developed. This transformation provides a new strategy for the installation of amino and nitro from aromatic amines and nitro-paraffin into alkenes. Morpholine resulted in the aza-Henry reaction, while DABCO led to the unexpected rearrangement.