72269-48-8Relevant articles and documents
Fe-catalyzed synthesis of (4E)-tridec-4-en-1-yl acetate, sex pheromone of tomato pinworm (Keiferia lycopersicella)
Shakhmaev,Sunagatullina,Zorin
, p. 669 - 671 (2013/07/19)
Starting with industrially available 1,3-dichloropropene a stereoselective process was developed for the preparation of (4E)-tridec-4-en-1-yl acetate, sex pheromone of tomato pinworm (Keiferia lycopersicella) using in the key stage the Fe-catalyzed cross-coupling of ethyl (4E)-5-chloropent-4-enoate with octylmagnesium bromide.
Acetylcyclopropane as a Five-Carbon Building Block in the Synthesis of some Acetogenin Insect Pheromones
Moiseenkov, Alexander M.,Czeskis, Boris A.,Ivanova, Natalya M.,Nefedov, Oleg M.
, p. 2639 - 2649 (2007/10/02)
Interaction of deprotonated acetylcyclopropane cyclohexylimine with several aliphatic alkyl halides, epoxides, and aldehydes efficiently gave the corresponding cyclopropyl ketones.Some of the respectible alcohols were rearranged in a highly stereoselective manner under the action of trimethylsilyl bromide in the presence of zinc bromide into the corresponding linear (E)-homoallyl bromides.The latter were used, in turn, as key intermediates in concise syntheses of thirteen terminally functionalized straight-chain oligoolefins which are known to constitute acetogenin pheromonal components for more than 65 species of lepidopteran insects.
LOW-MOLECULAR-MASS BIOREGULATORS. III. SYNTHESIS OF TRIDEC-4E-ENYL ACETATE-THE SEX PHEROMONE OF Keiferia lycopersicella
Melikyan, G. G.,Aslanyan, G. Kh.,Atanesyan, K. A.,Mkrtchyan, D. A.,Badanyan, Sh. O.
, p. 83 - 85 (2007/10/02)
A new method has been developed for the synthesis of tridec-4E-enyl acetate - the sex pheromone of the tomato pinworm Keiferia lycopersicella.