72310-28-2

Basic information

• Product Name: 2-CHLORONAPHTHO[1,8-D,E][1,3,2]DIOXAPHOSPHININE
• Synonyms: 2-CHLORONAPHTHO[1,8-D,E][1,3,2]DIOXAPHOSPHININE;2-Chloronaphtho[1,8-de]-1,3,2-dioxaphosphorin
• CAS NO: 72310-28-2
• Molecular Formula: C₁₀H₆ClO₂P
• Molecular Weight: 224.58
• Mol File: 72310-28-2.mol
• Article Data: 3

Chemical Properties

• Melting Point: 135-137℃
• Appearance: /
• CAS DataBase Reference: 2-CHLORONAPHTHO[1,8-D,E][1,3,2]DIOXAPHOSPHININE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-CHLORONAPHTHO[1,8-D,E][1,3,2]DIOXAPHOSPHININE(72310-28-2)
• EPA Substance Registry System: 2-CHLORONAPHTHO[1,8-D,E][1,3,2]DIOXAPHOSPHININE(72310-28-2)

Safety Data

• Hazardous Substances Data: 72310-28-2(Hazardous Substances Data)

Usage

General Description

2-CHLORONAPHTHO[1,8-D,E][1,3,2]DIOXAPHOSPHININE is a chemical compound with the molecular formula C16H9ClO2P. It is a phosphorous-based compound that contains a naphthalene ring with a chloro group attached. 2-CHLORONAPHTHO[1,8-D,E][1,3,2]DIOXAPHOSPHININE has potential applications in the field of organic chemistry, particularly in the synthesis of complex molecules. It may also have potential uses in materials science and as a building block for the creation of new chemical structures. Due to its unique chemical structure, 2-CHLORONAPHTHO[1,8-D,E][1,3,2]DIOXAPHOSPHININE may have diverse properties and potential applications in various fields of science and industry.

Upstream product

• 569-42-6 1,8-dihydroxynaphthalene 

Relevant articles and documents

Ring size effects in cyclic fluorophosphites: Ligands that span the bonding space between phosphites and PF3

The 5- to 8-membered cyclic fluorophosphites L5-8 have been prepared from the corresponding chlorophosphites which are derived from dihydroxyarenes or bis(trimethylsiloxy)arenes. Ligand L5 is very sensitive to hydrolysis but L6-8 are much more kinetically robust. The coordination chemistry of L5-8 has been explored with Mo(0), Pt(0) and Rh(i) and it is shown that the π-acceptor properties of L5-8 increase with decreasing ring size. The IR spectra and X-ray crystal structures of the [Mo(CO)4L2] complexes show that L5-8 lie between PF3 and P(OAr)3 in terms of their σ/π-bonding properties. The [PtL4] complexes are readily prepared from [Pt(nbe)3] and 4 equiv. of L5-8 whereas equilibrium mixtures of PtLx(nbe)y species form when 2 equiv. of L5-8 are added to [Pt(nbe)3]. The CO substitution reactions of [Rh2Cl2(CO)4] with L5-8 to give [Rh2Cl2L4] are evidence of the PF3-like ligand properties of L5-8. The trends in the properties of L5-8 are analysed in terms of their proximity to PF3 or P(OPh)3.

SYNTHESIS AND INVESTIGATION OF 1,8- AND 1,2-NAPHTHYLENE PHOSPHITES

-