72331-76-1

Basic information

• Product Name: 1,2-Propanediol, 2-phenyl-, 1-acetate
• CAS NO: 72331-76-1
• Molecular Formula: C11H14O3
• Molecular Weight: 194.23
• Mol File: 72331-76-1.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: 1,2-Propanediol, 2-phenyl-, 1-acetate(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-Propanediol, 2-phenyl-, 1-acetate(72331-76-1)
• EPA Substance Registry System: 1,2-Propanediol, 2-phenyl-, 1-acetate(72331-76-1)

Safety Data

• Hazardous Substances Data: 72331-76-1(Hazardous Substances Data)

Upstream product

• 230972-65-3 tert-butyl (2-phenyl-1-acetoxy-prop-2-yl) peroxide 
• 98-83-9 isopropenylbenzene 
• 2085-88-3 2-methyl-2-phenyloxirane 
• 141-78-6 ethyl acetate 
• 4217-66-7 1,2-dihydroxy-2-phenylpropane 
• 80-43-3 bis(1-methyl-1-phenylethyl)peroxide 
• 64-19-7 acetic acid 
• 3457-61-2 tert-butyl cumyl peroxide 
• 108-24-7 acetic anhydride 
• 98-82-8 Isopropylbenzene 
• 75-05-8 acetonitrile 

Downstream Products

• 21129-05-5 2-phenylpropane-1,2-diyl diacetate 
• 7534-40-9 2-phenylallyl acetate 
• 4217-66-7 1,2-dihydroxy-2-phenylpropane 
• 187931-00-6 3-acetoxy-1,2-dihydroxy-2-phenylpropane 
• 95971-76-9 3-acetyl-2-hydroxy-2-phenylpropyl acetate 

Relevant articles and documents

Chemo-, regio-, and stereoselective synthesis of syn -aryl glycol monoesters from aryl olefins with hydrogen peroxide catalyzed by RuCl 3

Chemo-, regio-, and stereoselectivity have been achieved in the oxidations of aryl olefins. The aryl olefins were oxidized by 2 equivalents of H 2O2 in acetic acid, catalyzed by 0.02 equivalent of RuCl3, leading to the formations of syn-aryl glycol monoesters. As the reaction is concerted, both the regio- and stereoselectivity are excellent. In the presence of aliphatic C=C bonds, the aryl C=C bonds were selectively dioxygenated. This represents the first example of chemoselective dioxygenation of aryl C=C bonds. Georg Thieme Verlag Stuttgart - New York.

A rapid 1,2-dihydroxylation of alkenes using a lipase and hydrogen peroxide under microwave conditions

The combined advantages of using an enzyme immobilized lipase from Pseudomonas sp [PSLG6], hydrogen peroxide, ethyl acetate and microwave irradiation for the dihydroxylation of olefins are reported.

Dialkyl peroxides decomposition in the presence of quaternary ammonium halides

Decomposition of dicumyl peroxide and cumyl tert-butyl peroxide was studied in the presence of tetraethylammonium halides in acetonitrile, dimethylformamide, 2-propanol, and acetic acid. The tetraethylammonium halides accelerate the decomposition of dialkyl peroxides in 2-propanol and acetic acid, but do not affect the reaction velocity in dimethylformamide and acetonitrile. The decomposition products character depends on the solvent nature.