72450-41-0

Basic information

• Product Name: benzyl <1-13C>acetate
• Synonyms: benzyl <1-13C>acetate
• CAS NO: 72450-41-0
• Molecular Weight: 151.166
• Mol File: 72450-41-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: benzyl <1-13C>acetate(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl <1-13C>acetate(72450-41-0)
• EPA Substance Registry System: benzyl <1-13C>acetate(72450-41-0)

Safety Data

• Hazardous Substances Data: 72450-41-0(Hazardous Substances Data)

Upstream product

• 1563-79-7 [1-13C]-acetic acid 
• 100-51-6 benzyl alcohol 
• 100-39-0 benzyl bromide 
• 23424-28-4 sodium acetate 
• 100-44-7 benzyl chloride 

Downstream Products

• 155060-64-3 benzyl <1-13C>-3-oxo-octanoate 
• 72450-42-1 benzyl [1,3-13C₂]acetoacetate 
• 419542-83-9 1-benzyl 4-tert-butyl [1-13C]succinate 

Relevant articles and documents

Enzymatic Synthesis of Methylated Terpene Analogues Using the Plasticity of Bacterial Terpene Synthases

Methylated analogues of isopentenyl diphosphate were synthesised and enzymatically incorporated into methylated terpenes. A detailed stereochemical analysis of the obtained products is presented. The methylated terpene precursors were also used in conjunction with various isotopic labellings to gain insights into the mechanisms of their enzymatic formation.

Biosynthesis of the indolizidine alkaloid cyclizidine: incorporation of singly and doubly labelled precursors

Incorporation of CH313C18O2Na and CD3CH213CO2Na into the indolizidine alkaloid cyclizidine 1, produced by Streptomyces species NCIB 11649, shows that the oxygen attached to C-2 is derived intact from acetate and that the cyclopropyl ring is derived from a single intact propionate unit.However, the level and stereochemistry of the incorporation of deuteriated sodium propionate indicates that it undergoes unexpected modification during incorporation into the cyclopropyl ring.