7263-45-8

Basic information

• Product Name: silver salt of N-nitroso-N-phenylhydroxylamine
• Synonyms: silver salt of N-nitroso-N-phenylhydroxylamine
• CAS NO: 7263-45-8
• Molecular Weight: 244.986
• Mol File: 7263-45-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: silver salt of N-nitroso-N-phenylhydroxylamine(CAS DataBase Reference)
• NIST Chemistry Reference: silver salt of N-nitroso-N-phenylhydroxylamine(7263-45-8)
• EPA Substance Registry System: silver salt of N-nitroso-N-phenylhydroxylamine(7263-45-8)

Safety Data

• Hazardous Substances Data: 7263-45-8(Hazardous Substances Data)

Downstream Products

• 96345-28-7 [Pd(ON(C₆H₅)NO)(P(C₆H₅)3)2]⁽¹⁺⁾*PF₆^(1-)=[Pd(ON(C₆H₅)NO)(P(C₆H₅)3)2]PF₆ 
• 96345-24-3 [Pt(ON(C₆H₅)NO)(P(C₆H₅)3)2]⁽¹⁺⁾*PF₆^(1-)=[Pt(ON(C₆H₅)NO)(P(C₆H₅)3)2]PF₆ 
• 10102-43-9 nitrogen(II) oxide 
• 7440-22-4 silver 
• 586-96-9 Nitrosobenzene 
• 74103-26-7 1-tert-butyl-3-phenyloxadiazene 3-oxide 
• 4504-08-9 p-nitrophenyl-N,N,O-azoxybenzene 
• 768-95-6 1-adamanthanol 
• 74103-27-8 1-(1-adamantyl)-3-phenyloxadiazene 3-oxide 
• 171203-60-4 (η(2)-N-phenyl-N-nitrosohydroxylaminato)(meso-tetrakis(p-methoxyphenyl)porphyrinato)iron(III) 

Relevant articles and documents

Metal Complexes of N-Aryl-N-nitrosohydroxylamines: Cleavage of N-N Bonds to give Metal Nitrosyl Species and Organonitrogen Compounds, and the Crystal Structure of (H2O)(PPh3)>*0.5Me2CO

Reaction of ,, , , and with Q (Q=NH4 or Ag; R=Ph or C6H4Me-p) afforded > (L=PPh3 or CO), >, 2(PPh3)2>, and (PPh3)>.Reaction of (PPh3)2> with I2 gave x(PPh3)2>n> (R=Ph, x=2, n=1; R=C6H4Me-p, x=1, n=unknown), and with CO gave (PPh3)>.The latter was also prepared from > and PPh3.Treatment of (PPh3)2> and 2(PPh3)2> with RhCl3 and RuCl3 afforded (H2O)(PPh3)> and 2(PPh3)2>, respectively.The structure of (H2O)(PPh3)>*0.5Me2CO was determined crystallographically, and the metal shown to be six-co-ordinate with a chelating N-aryl-N-nitrosohydroxylaminato ligand and water.Treatment of (PPh3)>, (PPh3)2>, and 2(PPh3)2> with HCl gave , , and , respectively, and the organic products obtained from the complexes of Rh and Ru identified by gas chromatography and mass spectrometry as p-MeC6H4NO, p-MeC6H4NH2 (major component), and C6H3Me(NH2)Cl.A possible mechanism of formation of the nitrosyl complexes and organonitrogen compounds is briefly discussed.