7287-06-1

Basic information

• Product Name: Cyclooctanol, 1-phenyl-
• CAS NO: 7287-06-1
• Molecular Formula: C14H20O
• Molecular Weight: 204.312
• Mol File: 7287-06-1.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Cyclooctanol, 1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclooctanol, 1-phenyl-(7287-06-1)
• EPA Substance Registry System: Cyclooctanol, 1-phenyl-(7287-06-1)

Safety Data

• Hazardous Substances Data: 7287-06-1(Hazardous Substances Data)

Upstream product

• 502-49-8 cycloactanone 
• 696-71-9 cyclooctanol 
• 100-58-3 phenylmagnesium bromide 
• 749893-57-0 1-propylcyclooctanol 
• 100-59-4 phenylmagnesium chloride 
• 108-86-1 bromobenzene 
• 16538-85-5 phenylcyclooctane 

Downstream Products

• 59358-73-5 1,1'-Diphenyl-1,1'-bicyclooctyl 
• 16538-85-5 phenylcyclooctane 
• 1674-37-9 n-octanophenone 
• 137407-47-7 (E)-1-phenylcyclooctene 
• 76393-73-2 1-phenylcyclooctyl cation 
• 79798-02-0 1-phenylcyclooctyl azide 
• 14630-74-1 1-phenyl-4-cycloocten-1-ol 
• 14573-46-7 8-iodo-1-phenyloctan-1-one 
• 92-52-4 biphenyl 
• 25328-90-9 1-phenylcyclooct-1-ene 
• 65-85-0 benzoic acid 
• 78712-57-9 8-bromo-1-phenyloctan-1-one 

Relevant articles and documents

Iodobenzene-catalyzed oxidative cleavage of olefins to carbonyl compounds

A metal-free approach for the oxidative cleavage of carbon–carbon double bonds of olefins to carbonyl compounds was established by using oxidant m-CPBA and non-metallic organocatalyst PhI in toluene/H2O. A broad scope of aromatic olefins was used. All the reactions proceeded smoothly at 35 °C in short reaction time to furnish the respective mono- and double carbonyl compounds selectively in moderate to good yields.

NOVEL COMPOUNDS 514

The invention provides compounds of formula (I), wherein R1, R2, R3, R4, R5, g, h and X are as defined in the specification, a process for their preparation, pharmaceutical compositions containing the

Photolysis of 1-alkylcycloalkanols in the presence of (diacetoxyiodo) benzene and I2. Intramolecular selectivity in the β-scission reactions of the intermediate 1-alkylcycloalkoxyl radicals

The C-C β-scission reactions of 1-alkylcycloalkoxyl radicals, generated photochemically by visible light irradiation of CH2Cl 2 solutions containing the parent 1-alkylcycloalkanols, (diacetoxy)-iodobenzene (DIB), and I2, have been investigated through the analysis of the reaction products. The 1-alkylcycloalkoxyl radicals undergo competition between ring opening and C-alkyl bond cleavage as a function of ring size and of the nature of the alkyl substituent. With the 1-propylcycloheptoxyl, 1-propylcyclooctoxyl, and 1-phenylcyclooctoxyl radicals, formation of products deriving from an intramolecular 1,5-hydrogen atom abstraction reaction from the cycloalkane ring has also been observed. The results are discussed in terms of release of ring strain associated to ring opening, stability of the alkyl radical formed by C-alkyl cleavage, and with cycloheptoxyl and cyclooctoxyl radicals, also in terms of the possibility of achieving a favorable geometry for intramolecular hydrogen atom abstraction.