72927-80-1Relevant articles and documents
Synthesis method of phenylacetaldehyde derivative
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Paragraph 0034; 0039-0040, (2021/08/07)
The present invention discloses a synthesis method of phenylacetaldehyde derivative, a benzaldehyde derivative is adopted as a raw material, an intermediate 2-methoxyvinylphenyl derivative is obtained through synthesis, then the phenylacetaldehyde derivative is obtained through synthesis, and the substituent group R of the benzaldehyde derivative includes but is not limited to m-methyl, m-ethyl, m-nitrile group, p-methyl, o-methyl, o-nitro and 2, 6-dimethyl. The synthesis process is simple, synthesis conditions are mild, post-treatment is relatively simple, and industrial production is easy; the universality is good, and substrates with different functional groups are compatible; the yield is considerable, part of compounds are almost quantitatively converted, and the requirement of atom economy is met.
Peroxygenase-Catalysed Epoxidation of Styrene Derivatives in Neat Reaction Media
Alcalde, Miguel,Arends, Isabel W. C. E.,Hollmann, Frank,Paul, Caroline E.,Rauch, Marine C. R.,Tieves, Florian
, (2019/08/30)
Biocatalytic oxyfunctionalisation reactions are traditionally conducted in aqueous media limiting their production yield. Here we report the application of a peroxygenase in neat reaction conditions reaching product concentrations of up to 360 mM.
Application of an electron-transfer catalyst in light-induced aerobic oxidation of alcohols
Guo, Rui-Yun,Sun, Li,Pan, Xin-Yi,Yang, Xiao-Dong,Ma, Shuai,Zhang, Jie
, p. 12614 - 12617 (2018/11/20)
The first heterogeneous photocatalysis system including a bipyridinium-based complex as the electron-transfer catalyst was developed for aerobic oxidation of alcohols without the use of any noble-metal, external N-oxide or peroxide co-oxidant. The current work provides an efficient strategy for alcohol oxidation through a cost-effective, convenient and eco-friendly route.