729559-13-1

Basic information

• Product Name: (NE)-N-(cyclohexylmethylene)-2-methylpropane-2-sulfinamide
• Synonyms: (NE)-N-(cyclohexylmethylene)-2-methylpropane-2-sulfinamide
• CAS NO: 729559-13-1
• Molecular Weight: 215.36
• Mol File: 729559-13-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (NE)-N-(cyclohexylmethylene)-2-methylpropane-2-sulfinamide(CAS DataBase Reference)
• NIST Chemistry Reference: (NE)-N-(cyclohexylmethylene)-2-methylpropane-2-sulfinamide(729559-13-1)
• EPA Substance Registry System: (NE)-N-(cyclohexylmethylene)-2-methylpropane-2-sulfinamide(729559-13-1)

Safety Data

• Hazardous Substances Data: 729559-13-1(Hazardous Substances Data)

Upstream product

• 146374-27-8 S-tert-butylsulfinimide 
• 2043-61-0 cyclohexanecarbaldehyde 

Downstream Products

• 849178-88-7 [1-cyclohexyl-2-(dimethyl-phenyl-silanyl)-ethyl]-carbamic acid tert-butyl ester 
• 188348-00-7 (R)-1-(cyclohexyl-2-hydroxyethyl)carbamic acid tert-butyl ester 
• 849178-79-6 2-Methyl-propane-2-sulfinic acid [(R)-1-cyclohexyl-2-(dimethyl-phenyl-silanyl)-ethyl]-amide 

Relevant articles and documents

Ring-Opening of N-tert-Butanesulfinylethynylaziridines with Lithium Tris(dimethylphenylsilyl)zincate: Stereoselective Access to 4-Amino-1-allenylsilanes

The ring-opening of N-tert-butanesulfinylethynylaziridines with lithium tris(dimethylphenylsilyl)zincate is reported. The reaction is demonstrated to be both stereoselective and stereospecific and to proceed through an anti-SN2′ process. Further deprotection of the nitrogen atom under mild conditions allows access to 4-amino-1-(dimethylphenylsilyl)allenes with high yields and levels of stereoselectivity.

Conformationally Driven Two- and Three-Photon Cascade Processes in the Stereoselective Photorearrangement of Pyrroles

A TBSO group has been shown to exert a high degree of stereocontrol during the two-photon photocycloaddition/rearrangement of N-butenylpyrroles to complex tricyclic aziridines. Moreover, this and other bulky groups have been shown to change the outcome of the reaction, promoting a new two-photon sequence to tricyclic imines and an unprecedented stereoselective three-photon sequence to azabicyclo[3.3.1]nonanes.