729580-61-4Relevant articles and documents
Method for preparing 4-acetylenic ketone/ester compound and application thereof
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Paragraph 0078-0081; 0082; 0083; 0084; 0085; 0087; 0097, (2020/06/20)
The invention relates to a method for preparing a 4-acetylenic ketone/ester compound and an application thereof, and particularly provides a preparation method of a copper-mediated 4-acetylenic ketone/ester compound. The process is mild in reaction conditions and good in yield, and the compound has strong functional group tolerance and good compatibility.
Direct conjugate addition of alkynes with α,β-unsaturated carbonyl compounds catalyzed by NCN-pincer Ru complexes
Ito, Jun-Ichi,Fujii, Kohei,Nishiyama, Hisao
supporting information, p. 601 - 605 (2013/03/13)
NCN-pincer Ru-complexes containing bis(oxazolinyl)phenyl ligands serve as suitable catalysts in the direct conjugate additions of α,β- unsaturated carbonyl compounds, including ketones, esters, and amides, as well as vinylphosphonates, giving various β-alkynyl carbonyl and phosphonate compounds. A bis(oxazolinyl)phenyl (phebox)-Ru complex also catalyzes the asymmetric conjugate addition of an alkyne with a β-substituted, α,β-unsaturated ketone to produce a chiral β-alkynyl ketone. Copyright
An effective synthetic entry to fused benzimidazoles via iodocyclization
Zhang, Xu,Zhou, Yu,Wang, Hengshuai,Guo, Diliang,Ye, Deju,Xu, Yungen,Jiang, Hualiang,Liu, Hong
, p. 1429 - 1437 (2011/08/03)
A protocol for the synthesis of the fused heterocyclic polycyclic compounds pyrrole[1,2-a]benzimidazoles, piperidine[1,2-a]benzimidazoles and oxa-fused benzimidazoles using iodine and silver nitrate by an exo-dig or endo-dig cyclization pathway at room te