7309-52-6 Usage
General Description
2-(3-METHOXY-PHENOXY)-PROPIONIC ACID, often abbreviated as MPPA, is a synthetic chemical compound mainly belonging to the category of Phenoxy Carboxylic Acids. Being a relatively complex molecule derived from phenol, it contains a propionic acid chain and a phenol ring with a methoxy group attached. Its noteworthy attributes include its role in organic synthesis and potential application in biochemistry for medicinal and drug discovery research. The exact physical properties may vary depending on its specific formulation, but it's generally considered to have stability under normal temperatures and pressures. However, it may pose certain health hazards or environmental impacts depending on its handling and use.
Check Digit Verification of cas no
The CAS Registry Mumber 7309-52-6 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 7,3,0 and 9 respectively; the second part has 2 digits, 5 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 7309-52:
(6*7)+(5*3)+(4*0)+(3*9)+(2*5)+(1*2)=96
96 % 10 = 6
So 7309-52-6 is a valid CAS Registry Number.
InChI:InChI=1/C10H12O4/c1-7(10(11)12)14-9-5-3-4-8(6-9)13-2/h3-7H,1-2H3,(H,11,12)
7309-52-6Relevant articles and documents
Access to Optically Enriched α-Aryloxycarboxylic Esters via Carbene-Catalyzed Dynamic Kinetic Resolution and Transesterification
Liu, Bin,Song, Runjiang,Xu, Jun,Majhi, Pankaj Kumar,Yang, Xing,Yang, Song,Jin, Zhichao,Chi, Yonggui Robin
supporting information, p. 3335 - 3338 (2020/04/30)
Optically active α-aryloxycarboxylic acids and their derivatives are important functional molecules. Disclosed here is a carbene-catalyzed dynamic kinetic resolution and transesterification reaction for access to this class of molecules with up to 99% yields and 99:1 er values. Addition of a chiral carbene catalyst to the ester substrate leads to two diastereomeric azolium ester intermediates that can quickly epimerize to each other and thus allows for effective dynamic kinetic resolution to be realized. The optically enriched ester products from our reaction can be quickly transformed to chiral herbicides and other bioactive molecules.
