73190-70-2Relevant articles and documents
Palladium-catalyzed carbonylation of benzylic ammonium salts to amides and esters: Via C-N bond activation
Yu, Weijie,Yang, Shuwu,Xiong, Fei,Fan, Tianxiang,Feng, Yan,Huang, Yuanyuan,Fu, Junkai,Wang, Tao
supporting information, p. 3099 - 3103 (2018/05/22)
An efficient palladium-catalyzed carbonylation reaction of readily available quaternary ammonium salts with CO is reported for the first time to afford arylacetamides and arylacetic acid esters via benzylic C-N bond cleavage. This protocol features mild reaction conditions under atmospheric pressure of CO, a redox-neutral process without an additional oxidant, and a broad substrate scope for various kinds of amines, alcohols and phenols.
Triethyl phosphite-p-dimethylaminopyridine, a new reagent for direct syntheses of amides from aliphatic carboxylic acids and amines
Chiriac, Constantin I.,Onciu, Marioara,Tǎnasǎ, Fulga,Bǎdǎrǎu, Cristina,Tru?can, Ion
, p. 971 - 974 (2007/10/03)
Various amides have been prepared with high to moderate yields from the corresponding aliphatic carboxylic acids and amines using triethyl phosphite-p-dimethylaminopyridine as a new reagent and pyridine as solvent, at 100-110°C, for 12 hours.