7326-47-8Relevant articles and documents
New reactions of anticancer-platinum complexes and their intriguing behaviour under various experimental conditions
Aleman, Jose,Del Solar, Virginia,Cubo, Leticia,Quiroga, Adoracion G.,Navarro Ranninger, Carmen
experimental part, p. 10601 - 10607 (2011/01/05)
The anticancer platinum complexes here described react with organic substrates (such as acids, alkenes, alkynes) and catalyze transformations that can occur in biomolecules which contain unsaturated functions. We have analyzed the role of the platinum complexes in the observed reactions and studied the progress of the detected transformations upon variation of the reaction conditions. The Royal Society of Chemistry 2010.
RADIATION-INITIATED ADDITION OF ACETALDEHYDE TO ALLYL ALCOHOL AND CONVERSION OF THE 1:2-TELOMER INTO 1-METHYL-2,8-DIOXABICYCLONONANE
Liska, Frantisek,Fikar, Jiri,Trska, Petr,Valenta, Miroslav
, p. 3278 - 3283 (2007/10/02)
Radiation-initiated addition of acetaldehyde to allyl alcohol gave a mixture of 5-hydroxy-2-pentanone (1:1-aduct I), 2-methyl-2-(4-oxopentyloxy)tetrahydrofuran (II), 7-hydroxy-4-hydroxymethyl-2-heptanone (1:2-telomer III) and 1,1-bis(4-oxopentyloxy)ethane (IV).The telomer III was dehydrated to afford 3-acetonyltetrahydropyran (V), 1-methyl-2,8-dioxabicyclononane (VI) and 3,10-dimethyl-4,11,16,17-tetraoxatricyclo3,8>octadecane (VII).
