73296-31-8

Basic information

• Product Name: Silane, trimethyl(phenyltelluro)-
• CAS NO: 73296-31-8
• Molecular Formula: C9H14SiTe
• Molecular Weight: 277.896
• Mol File: 73296-31-8.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl(phenyltelluro)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl(phenyltelluro)-(73296-31-8)
• EPA Substance Registry System: Silane, trimethyl(phenyltelluro)-(73296-31-8)

Safety Data

• Hazardous Substances Data: 73296-31-8(Hazardous Substances Data)

Upstream product

• 109-99-9 tetrahydrofuran 
• 75-77-4 chloro-trimethyl-silane 
• 100-58-3 phenylmagnesium bromide 
• 41422-67-7 sodium phenyltelluride 
• 14683-12-6 tellurium 
• 591-51-5 phenyllithium 
• 629-05-0 n-octyne 
• 194346-19-5 (C₁₂H₉)TePt(P(C₂H₅)3)2Si(CH₃)3 
• 32294-60-3 diphenyl ditelluride 

Downstream Products

• 96185-55-6 Trimethyl-(3-phenyltellanyl-propoxy)-silane 
• 91489-38-2 4-(phenyltelluro)butyl trimethylsilyl ether 
• 96185-57-8 Trimethyl-(5-phenyltellanyl-pentyloxy)-silane 
• 96185-58-9 Trimethyl-(6-phenyltellanyl-hexyloxy)-silane 
• 96185-51-2 6-Phenyltellanyl-hexanoic acid 
• 1825-61-2 Trimethylmethoxysilane 
• 872-89-9 methylphenyltelluride 
• 14642-79-6 benzyloxy-trimethylsilane 
• 32344-00-6 benzyl phenyl telluride 
• 32343-98-9 n-butyl(phenyl)tellane 
• 96185-52-3 Trimethyl-((1R,2R)-2-phenyltellanyl-cyclohexyloxy)-silane 
• 420-56-4 trimethylsilyl fluoride 
• 32294-60-3 diphenyl ditelluride 
• 138786-08-0 2,3-Dimethoxy-5-methyl-1,4-bis-trimethylsilanyloxy-benzene 

Relevant articles and documents

Syntheses and Structures of Zinc(tmeda)bis(aryltellurolato) and its Facile Chalcogenospecific Ligand Exchange Reactivity

Anaerobic treatment of Zn(tmeda)Br2, where tmeda denotes N,N,N′,N′-tetramethylethylenediamine, with a solution of Na(TeAr), sodium aryltellurolate, in ethanol in a 1:2 stoichiometry led to the formation of highly air sensitive Zn(tmeda)(TeAr)2 (1–3), while a 1:1 stoichiometry afforded Zn(tmeda)Br(TeAr) (4). Crystallography revealed all complexes to be monomeric with four coordinate central zinc atoms bound to tmeda and two TeAr, or a TeAr and a Br ligand. Upon mixing two symmetrically substituted Zn(tmeda)(TeAr)2 complexes in solution, 125Te NMR revealed a facile ligand exchange providing Zn(tmeda)(TeAr)(TeAr′). In addition, Zn(tmeda)(TeAr)(TeAr′) complexes form on mixing symmetric Zn(tmeda)(TeAr)2 complexes and (TeAr′)2. The lability of the zinc complexes was put to advantage in ligand-substitution reactions wherein treatment of SnCl4 with Zn(tmeda)(TeAr)2 affords Sn(TeAr)4 in excellent yields without the concurrent formation of the redox product (TeAr)2. The apparent lability of the Zn–Te bond prevented the volatilization of 1–3 for their use as chemical vapor deposition precursors for the fabrication of ZnTe thin films. On heating, to volatize the complexes, the complexes decompose to cubic ZnTe and TeAr2 sublimes from the samples. Thermal gravimetric analysis indicates the loss of tmeda followed by the loss of TeAr2.

Synthesis and Crystal Structures of Copper Zinc Phenylthiolate and the First Copper Zinc Selenolate and Tellurolate Complexes

Five copper zinc phenylchalcogenolate complexes [(iPr3PCu)3(ZnMe2)2(SPh)3] (1), [(iPr3PCu)2(ZnPh)4(SPh)6] (2), [(iPr3PCu)2(ZnEt)4(SPh)6] (3), [(iPr3PCu)3(ZnEt)(SePh)4] (4), and [(iPr3PCu)3Cu(iPr3PZn)(TePh)6] (5) were synthesized by the reaction of phosphine stabilized copper phenylchalcogenolate complexes with ZnR2 (R = Me, Et, Ph) with and without additional chalcogenol. The novel mixed metal compounds were characterized by single-crystal X-ray structure analysis and NMR spectroscopy. 4 and 5 are the first examples of compounds with a Zn–Se–Cu or a Zn–Te–Cu linkage, respectively.

NUCLEOPHILIC CLEAVAGES OF ESTERS AND ETHERS WITH PHENYLTELLUROTRIMETHYLSILANE

The title tellurosilane 1 reacted with esters and ethers in the presence of catalytic zinc iodide under very mild conditions, giving the corresponding products with C-telluration and O-silylation via nucleophilic cleavages of the C-O bonds.