73318-99-7

Basic information

• Product Name: Ethanone, 1-[4-(ethylamino)phenyl]- (9CI)
• Synonyms: Ethanone, 1-[4-(ethylamino)phenyl]- (9CI)
• CAS NO: 73318-99-7
• Molecular Formula: C₁₀H₁₃NO
• Molecular Weight: 163.21632
• Product Categories: ACETYLGROUP
• Mol File: 73318-99-7.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 296°C at 760 mmHg
• Flash Point: 126.4°C
• Appearance: /
• Density: 1.04g/cm³
• Vapor Pressure: 0.00148mmHg at 25°C
• Refractive Index: 1.557
• CAS DataBase Reference: Ethanone, 1-[4-(ethylamino)phenyl]- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-[4-(ethylamino)phenyl]- (9CI)(73318-99-7)
• EPA Substance Registry System: Ethanone, 1-[4-(ethylamino)phenyl]- (9CI)(73318-99-7)

Safety Data

• Hazardous Substances Data: 73318-99-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H13NO/c1-3-11-10-6-4-9(5-7-10)8(2)12/h4-7,11H,3H2,1-2H3

Upstream product

• 64-67-5 diethyl sulfate 
• 99-92-3 p-aminobenzophenone 
• 103-69-5 N-ethyl-N-phenylamine 
• 75-36-5 acetyl chloride 
• 403-42-9 1-(4-fluorophenyl)ethanone 
• 75-04-7 ethylamine 
• 5520-66-1 4-(N,N-diethylamino)acetophenone 
• 99-90-1 para-bromoacetophenone 
• 2719-21-3 4-(N-acetylamino)acetophenone 
• 110-88-3 1,3,5-Trioxan 

Downstream Products

• 1100787-21-0 1-[4-(N-ethyl-N-(tert-butyloxycarbonyl)amino)phenyl]ethanone 

Relevant articles and documents

N-alkylation using sodium triacetoxyborohydride with carboxylic acids as alkyl sources

A versatile N-alkylation was performed using sodium triacetoxyborohydride and carboxylic acid as an alkyl source. The combination of these reagents furnished products different from those given previously by a similar reaction. Moreover, the mild conditions of our method allowed some functional groups to remain through the reaction, whereas they would react and be converted into other moieties in the similar reductive N-alkylation reported previously. Herein, we provide a new procedure for the preparation of various compounds containing nitrogen atoms.

Gold catalysis coupled with visible light stimulation: Syntheses of functionalized indoles

A judicious combination of Au-catalysis and synergistic visible-light stimulation formulates an exceptionally simple and mild reaction system capable of directly coupling anilines and alkynes to form multifunctionalized indoles.

Synthesis of new 1-[4-methane(amino)sulfonylphenyl]-5-[4-(aminophenyl)]-3- trifluoromethyl-1H-pyrazoles

(Chemical Equation Presented) A regiospecific cyclization-dehydration reaction of a 1-[4-(N-alkyl-N-(tert-butyloxycarbonyl)amino)-phenyl]-4,4,4- trifluorobutane-1,3-done with a 4-aminosulfonyl-, or 4-methylsulfonyl-, phenylhydrazine hydrochloride in refluxing ethanol proceeded with simultaneous loss of the N-tert-butyloxycarbonyl protecting group to afford a group of 1-(4-methanesulfonylphenyl or 4-aminosulfonylphenyl)-5-[4-(N-alkylaminophenyl)]- 3-(trifluoromethyl)-1H-pyrazoles (6). Subsequent reaction of the pyrazole 6 (R1 = R2 = Me) with nitric oxide (40 psi) proceeded via a N-methylamino-N-diazen-1-ium-1,2-diolate intermediate that undergoes protonation of the more basic diazen-1-ium-1,2-diolate N2-nitrogen and then loss of a nitroxyl (HNO) species to furnish the N-nitroso product 7.