73323-53-2Relevant articles and documents
Stereochemical Study on Nitro Tautomerization of Nitronate Adducts from Conjugate Addition of RMgX to a 4-Methoxy-1-nitronaphthalene System
Bartoli, Giuseppe,Bosco, Marcella,Baccolini, Graziano
, p. 2649 - 2653 (2007/10/02)
Addition of RMgX to 4-methoxy-1-nitronaphthalene (1) leads to formation of nitronate 1,4 adduct (2) together with lesser amounts of 1,6 addition product (3).On treatment with aqueous acetate-acetic acid buffer, 2 is converted into a nitronate anion which