73565-25-0Relevant articles and documents
1-Cyclohexyl-5-cyclohexylaminotetrazole
Govindasamy,Sundara Raj, S. Shanmuga,Velmurugan,Fun, Hoong-Kun
, p. 393 - 395 (1999)
The title compound, C13H23N5, consists of a planar tetrazole moiety and two cyclohexane rings substituted equatorially. Both cyclohexane rings adopt the chair conformation. The two cyclohexane rings are inclined to the mean plane of the tetrazole ring at 52.9(1) and 70.1(1)° and are at an angle of 74.5(1)° with each other. N-H. . .N and C-H. . .N hydrogen bonds join the molecules in chains running along the a axis.
Selective Gold-Catalysed Synthesis of Cyanamides and 1-Substituted 1H-Tetrazol-5-Amines from Isocyanides
?koch, Karel,Císa?ová, Ivana,?těpni?ka, Petr
supporting information, p. 13788 - 13791 (2018/09/14)
The newly discovered gold-catalysed reaction of isocyanides with hydrazoic acid generated in situ from trimethylsilyl azide and methanol (or, alternatively, from NaN3/AcOH) produces either cyanamides or 1-substituted 1H-tetrazol-5-amines, depending on the amount of available HN3. The reaction proceeds selectively and in generally high yields of either product, thus providing a particularly convenient access to a wide range of substituted 1H-tetrazol-5-amines that are rather difficult to access otherwise.
O -iodoxybenzoic acid mediated oxidative desulfurization initiated domino reactions for synthesis of azoles
Chaudhari, Pramod S.,Pathare, Sagar P.,Akamanchi, Krishnacharaya G.
experimental part, p. 3716 - 3723 (2012/06/16)
A systematic exploration of thiophilic ability of o-iodoxybenzoic acid (IBX) for oxidative desulfurization to trigger domino reactions leading to new methodologies for synthesis of different azoles is described. A variety of highly substituted oxadiazoles, thiadiazoles, triazoles, and tetrazoles have been successfully synthesized in good to excellent yields, starting from readily accessible thiosemicarbazides, bis-diarylthiourea, 1,3-disubtituted thiourea, and thioamides.