73718-62-4Relevant articles and documents
Synthesis and application of spiropyrane derivative probe for naked eye detection of chrome III
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, (2019/03/06)
The invention belongs to the technical fields of the preparation and application of biological probe materials and provides synthesis and application of a spiropyrane derivative probe for naked eye detection of chrome III. The spiropyrane derivative probe can be used for detecting chrome ions in a water solution and is prepared by linking benzimidazole as a chrome ion recognition group and hemicyanine as a fluorescent group through amino groups; and the chrome ions are recognized by the steps of inducing breakage of spiropyrane C-O through complexing and coordination with benzimidazole, and carrying out ring-opening fluorescence emission. The structural formula of the probe is as follows: formula (shown in the description), SP for short. The probe can be used for selectively detecting thechrome ions; and ultraviolet spectrograms of solutions acting with different metal ions show that the changes of the ultraviolet spectrograms are most obvious only after the probe is bound with the chromium ions, and the color of the solution of the chromium ions and the probe is changed from colorless to obviously red.
A photosensitive color-changing material and its color-changing in the dress material application (by machine translation)
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Paragraph 0067; 0068; 0070, (2017/08/14)
The present invention provides a novel structure containing Schiff base unit of spiral wicked qinqin kind of type I compounds, the compound is a photosensitive color-changing material of a small organic molecule. The invention also provides a synthetic method of containing the Schiff base unit piperazine compounds. The compounds of this invention can be used as a dye, to aldehyde fabric, is aldehyde fabric can be in the nature change color under the sunlight. (Type I). (by machine translation)
Colorimetric Cyanide Chemosensor Based on 1′,3,3′,4-Tetrahydrospiro[chromene-2,2′-indole]
Dagiliene, Migle,Martynaitis, Vytas,Kri??iuˉniene, Vilija,Krik?tolaityte, Sonata,?a?kus, Algirdas
, p. 363 - 369 (2015/06/30)
A new class of chemosensors based on the 1′,3,3′,4-tetrahydrospiro[chromene-2,2′-indole] ring system, which detects cyanide with high specificity, is described. These chemosensors show a distinct color change when treated with cyanide in acetonitrile solution buffered with sodium phosphate, and this procedure is not affected by the presence of other common anions. The chemisensors exhibit high sensitivity to low concentrations of cyanide, meeting the European Union water quality control criterion of sensitivity below 0.05 mg L-1, and show a very fast response within tens of seconds. The mechanism for detection is rationalized by the nucleophilic substitution of the phenolic oxygen atom at the indoline C-2 atom by the cyanide anion to form a stable indolylnitrile adduct and to generate the colored 4-nitrophenolate chromophore. These chemosensors can be synthesized by a simple procedure from commercially available starting materials.